in acetonitrile NaBPh4 added to soln. (Pt2(μ-H)2HPt(PEt3)4)(HCO2) in acetonitrile; ppt. filtered, solvent removed under vac., residue dissolved in acetone, methanol added and soln. cooled to -10°C for 48 h; elem. anal.;
参考文献
Paonessa, Ralph S.; Trogler, William C.
Inorganic Chemistry, 1983 , vol. 22, p. 1038 - 1048
potassium permanganate; sodium periodate; dihydrogen peroxide in tetrahydrofuran; water T=0°C; 12 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 3195 - 3208
in not given residue of react. is extracted with a mixt. of water and methanol or ethanol; relative pure NaHCO2-soln. is free of NaCO3 and Na4Fe(CN)6;;
hydrogen in neat (no solvent) byproducts: Cr(OH)3; reacting mixt. of CO and H2 at 40-50 atm. or town gas at 50-100 atm. at 250°C in stirring autoclave;;
