(E)-3,7-二甲基-2,6-辛二烯醛合成路线 （共 128 条）
反应条件
bis(cyclopentadienyl)titanium dichloride; zinc in tetrahydrofuran; water T=20°C; 6 h;
参考文献
Organic Letters, , vol. 8, # 24 p. 5433 - 5436
反应条件
hydrogen; H-β zeolite; iridium in isopropyl alcohol T=20°C; P=18001.4 Torr; 2.25 h; Title compound not separated from byproducts;
参考文献
De Bruyn, Mario; Coman, Simona; Bota, Roxana; Parvulescu, Vasile I.; De Vos, Dirk E.; Jacobs, Pierre A.
Angewandte Chemie - International Edition, 2003 , vol. 42, # 43 p. 5333 - 5336
反应条件
hydrogen in butan-1-ol T=25°C; P=1140.08 Torr;
参考文献
Wu, Binghui; Huang, Huaqi; Yang, Jing; Zheng, Nanfeng; Fu, Gang
Angewandte Chemie - International Edition, 2012 , vol. 51, # 14 p. 3440 - 3443
反应条件
hydrogen; monoaluminum phosphate; palladium matal-containing silica-supported catalyst in tetrahydrofuran T=29.9°C; P=3102.9 Torr; Ea, ΔH, ΔS; other Pd support, also in the presence of FeCl2; other solvents, var. pressure and temp.; Thermodynamic dataProduct distribution;
参考文献
Aramendia; Borau; Jimenez; Marinas; Porras; Urbano
Journal of Catalysis, 1997 , vol. 172, # 1 p. 46 - 54
反应条件
nickel sulphate; ammonium hydroxide; sodium hydroxide; dipotassium peroxodisulfate in water 6 h; Ambient temperature;
参考文献
Yamazaki, Shigakazu; Yamazaki, Yasuyuki
Chemistry Letters, 1990 , # 4 p. 571 - 574
参考文献
Carrara et al.
Gazzetta Chimica Italiana, 1953 , vol. 83, p. 459,470
Full Text Show Details
Libermann et al.
Bulletin de la Societe Chimique de France, 1954 , p. 1430,1434
Full Text Show Details
Efimovsky; Rumpf
Bulletin de la Societe Chimique de France, 1954 , p. 1401,1403
Full Text Show Details
Sah; Peoples
Journal of the American Pharmaceutical Association (1912-1977), 1954 , vol. 43, p. 513,514
反应条件
diethyl-1,4-dihydro-2,6-dimethyl-3,5-pyridine dicarboxylate; benzoic acid; (S)-2-(diphenyl(trimethylsilyloxy)methyl)pyrrolidine in chloroform T=-20°C; 63 h; Title compound not separated from byproducts;
参考文献
Hall, Melanie; Stueckler, Clemens; Kroutil, Wolfgang; Macheroux, Peter; Faber, Kurt
Angewandte Chemie - International Edition, 2007 , vol. 46, # 21 p. 3934 - 3937
反应条件
1: With methyl-diethoxy-silane; Rh<(S,S)-Phebox>(OAc)2(aq) in toluene T=30°C; 1 h; 2: With potassium fluoride; tetrabutyl ammonium fluoride in tetrahydrofuran; methanol; toluene Further stages.;
参考文献
Kanazawa, Yoshinori; Nishiyama, Hisao
Synlett, 2006 , # 19 p. 3343 - 3345
反应条件
1: sodium sulfite, 25percent sulfuric acid / H2O / 15 - 20 °C 2: sulfuric acid / H2O / 18 - 20 °C 3: 20percent sodium hydroxide / H2O / 5 - 7 °C 4: H2, potassium iodide / 50percent nickel/kieselguhr / aq. propan-2-ol / 112509 Torr View Scheme
参考文献
Erman, M. B.; Golovacheva, E. V.; Gulyi, S. E.; Zasetskii, D. L.; Shutikova, L. A.; et al.
Journal of Organic Chemistry USSR (English Translation), 1990 , vol. 26, # 2.1 p. 219 - 221
Zhurnal Organicheskoi Khimii, 1990 , vol. 26, # 2 p. 262 - 265
反应条件
glucose-6-phosphate dehydrogenase; glucose-6-phosphate; Saccharomyces pastorianus old yellow enzyme wild type; NADP T=20°C; 24 h; Enzymatic reaction; enantioselective reaction;
参考文献
Padhi, Santosh Kumar; Bougioukou, Despina J.; Stewart, Jon D.
Journal of the American Chemical Society, 2009 , vol. 131, p. 3271 - 3280
