顺-3,7-二甲基-2,6-辛二烯-1-醇乙酸酯合成路线 （共 54 条）
反应条件
samarium diiodide; isopropyl alcohol; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran 2 h; Heating; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Tabuchi, Takanori; Inanaga, Junji; Yamaguchi, Masaru
Tetrahedron Letters, 1986 , vol. 27, # 5 p. 601 - 602
反应条件
1: SeO2 / ethanol; pyridine / 1 h / Heating 2: NaBH4 / diethyl ether; methanol / 1 h 3: 79 percent / 1.) 98percent HCOOH; 2.) aq. KOH / 2.5 h / 20 °C 4: 231 mg / pyridine / 30 °C 5: 78 percent / LiAlH4 / diethyl ether / 0.5 h / Heating View Scheme
参考文献
Kitagawa, Isao; Tsujii, Shinji; Nishikawa, Fumiko; Shibuya, Hirotaka
Chemical & Pharmaceutical Bulletin, 1983 , vol. 31, # 8 p. 2639 - 2651
反应条件
P[2,4,6-(OMe)3C6H2]3 in methanol T=50°C; 24 h;
参考文献
Yoshimoto, Kazuya; Kawabata, Hirotoshi; Nakamichi, Natsuki; Hayashi, Masahiko
Chemistry Letters, 2001 , # 9 p. 934 - 935
反应条件
potassium hydroxide; Pd(PhCH=CH)2COgt;2CO; 1,2-bis-(diphenylphosphino)ethane in N,N-dimethyl-formamide Ambient temperature;
参考文献
Lebedev, S. A.; Starosel'skaya, L. F.; Petrov, E. S.
Journal of Organic Chemistry USSR (English Translation), 1986 , vol. 22, # 7 p. 1410
Zhurnal Organicheskoi Khimii, 1986 , vol. 22, # 7 p. 1565 - 1566
反应条件
1: 1.) Pd(PPh3)4, 90percent sodium azide / 1.) THF, water, 50 deg C, 2 h, 2.) THF, 50 deg C, 2 h 2: 2 N aq. NaOH / tetrahydrofuran / 1 h / 50 °C View Scheme
参考文献
Murahashi, Shun-Ichi; Taniguchi, Yuki; Imada, Yasushi; Tanigawa, Yoshio
Journal of Organic Chemistry, 1989 , vol. 54, # 14 p. 3292 - 3303
反应条件
triphenylphosphine; bis(dibenzylideneacetone)-palladium(0) in tetrahydrofuran T=60°C; 12 h; various allylic acetates, other borane, other amounts of NaBH4, other temp.; Product distribution;
参考文献
Legros, Jean-Yves; Fiaud, Jean-Claude
Tetrahedron Letters, 1990 , vol. 31, # 51 p. 7453 - 7456
反应条件
tetrakis(triphenylphosphine) palladium(0); 2-Propynylzinc bromide in tetrahydrofuran 3 h; Ambient temperature;
参考文献
Matsushita, Hajime; Negishi, Ei-ichi
Journal of Organic Chemistry, 1982 , vol. 47, # 21 p. 4161 - 4165
反应条件
in pentane 0.333333 h; Irradiationat 185 nm; Product distribution;
参考文献
Inoue, Yoshihisa; Goan, Kazuyoshi; Hakushi, Tadao
Bulletin of the Chemical Society of Japan, 1985 , vol. 58, # 8 p. 2217 - 2220
反应条件
formic acid; triethylamine; tris(dibenzylideneacetone)dipalladium(0) chloroform complex; tributylphosphine in tetrahydrofuran 4 h; Heating;
参考文献
Tsuji, Jiro; Minami, Ichiro; Shimizu, Isao
Synthesis, 1986 , # 8 p. 623 - 627
反应条件
sodium cyanoborohydride; triphenylphosphine; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran T=66°C; 44 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Hutchins, Robert O.; Learn, Keith; Fulton, Robert P.
Tetrahedron Letters, 1980 , vol. 21, p. 27 - 30
