monoethoxy-diethylaluminum; tri-iso-propyl phosphine; bis(acetylacetonato) palladium in toluene
T=100°C; 16 h; Yield given. Further byproducts given. Title compound not separated from byproducts;
bis(1,5-cyclooctadiene)nickel (0); triphenylphosphine in toluene
T=80 - 100°C; 5 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Binger, Paul; Wedemann, Petra
Tetrahedron Letters, 1985 , vol. 26, # 8 p. 1045 - 1048
tri-iso-propyl phosphine; (η3-allyl)(η5-Cp)Pd in toluene
T=110°C; 8 h; in dependence on catalyst, temperature, time, reagent, ratio of educts; Product distributionMechanism;
bei der Hydrolise der neutr.Fraktion mit methylalkoholisher Kalilauge und Reduktion des gewonnenen Produkts mit Zinkamalgam in saeurer Loesung.Hydrolysis;
参考文献
Ingold
Journal of the Chemical Society, 1925 , vol. 127, p. 1205
