in gas
Kinetics; byproducts: CF3(1+), CF2I(1+), CF3I(1+); further by-product: CF3; reaction of I(1+) (produced by electron impact on CF3I) with CF3I at 298 K;; not isolated; analysis in quadrupole mass spectrometer and detection by channel particle multiplier;;
参考文献
Morris, Robert A.; Doren, Jane M. Van; Viggiano, A. A.; Paulson, John F.
Journal of Chemical Physics, 1992 , vol. 97, # 1 p. 173 - 179
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反应条件
in gas
admitting F atoms (from an inlet tube) and iodide (from a heated glass crucible) to a blackened Al cell under reduced pressure;; detn. by visible chemiluminiscence in the range of 200-900nm (emitter IF);;
参考文献
Raybone, David; Watkinson, Timothy M.; Whitehead, J. Christopher
Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1987 , vol. 83, p. 767 - 774
in gas
admitting F atoms (from an inlet tube) and iodide (from a heated glass crucible) to a blackened Al cell under reduced pressure;; detn. by visible chemiluminiscence in the range of 200-900nm (emitter IF);;
参考文献
Raybone, David; Watkinson, Timothy M.; Whitehead, J. Christopher
Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1987 , vol. 83, p. 767 - 774
in gaseous matrix
Kinetics; byproducts: N2; other Radiation; pyrolysis by CO2-laser pulse; Ar as carrier gas; SF6 as sensitizer; visible spectra collected by a optical multichannel analyzer; UV emission;
参考文献
Benard, D. J.; Chowdhury, M. A.; Winker, B. K.; Seder, T. A.; Michels, H. H.
Journal of Physical Chemistry, 1990 , vol. 94, # 19 p. 7507 - 7514
in gas
admitting F atoms (from an inlet tube) and iodide (from a heated glass crucible) to a blackened Al cell under reduced pressure;; detn. by visible chemiluminiscence in the range of 425-800nm (emitter IF);;
参考文献
Raybone, David; Watkinson, Timothy M.; Whitehead, J. Christopher
Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1987 , vol. 83, p. 767 - 774
Kinetics; microwave discharge of F2 in He, flowing of resultant F atoms in a blackened Al-cell (0.6-1.8 mbar) with a glass crucible with BiI3 in it (373 K), flame react. with or without O2; chemiluminescence detn. of IF, fluorescence detn. of F atoms;
参考文献
Raybone, D.; Watkinson, T. M.; Whitehead, J. C.
Chemical Physics Letters, 1987 , vol. 135, p. 170 - 176
