in diethyl ether freshly prepared, moist AgN3 covered with water cooled to 0°C; addn. of soln. of I2 in ether cooled to 0°C under shaking;; decanting etheric layer at low temp. very fast through dry folder filter into flask with calcined Na2SO4; drying 5 min.; evapn. of ether with dry air until pptn., then in desiccator; washing with small amt. of petroleum ether; (drying); impurity: I2;;

in diethyl ether byproducts: AgI;

in water reaction of a suspension of AgN3 in H2O at 0°C with a solution of I2 in ether or benzene;;

in chloroform addn. of Sb-compd. to suspn. of azide, refluxing (24 h, pptn.); sepn. of ppt., filtration, distn. of solvent, recrystn. (petroleum ether);

in diethyl ether reaction of Cl2 with AgN3 in ether at ambient temp.;;

in diethyl ether passing Cl2 into suspension of AgN3 in ether at ambient temp.;;

in dichloromethane; benzene byproducts: AgCl; room temp., 12 h; AgCl was filtered off, the solvent was evapd.; elem. anal.;

in water addition of N(CH3)4I to a suspension of AgN3 in cold water;;

in dimethyl sulfoxide; acetonitrile T=20°C; 1 h; Inert atmosphere;

in neat (no solvent) byproducts: AgCl; freshly prepared Ag compd. under N2, evacuated, PCl3 vapor added at roomtremp.; PES;