chlorine in neat (no solvent) passing Cl2 and S2F10 through tube at 350°C;;

in neat (no solvent) ClOSO2F trasferred under vac. to FEP reactor fitted with stainless-steel valve and held at -196°C, SF4 condensed, reactor placed in bath at -90°C and allowed to warm to -40°C for 4 h; reactor cooled to -70°C, volatile materials(SF5Cl) removed, reactor warmed to -40°C and then - to 23°C and held under dynamic vac. for 10 min;

in neat (no solvent) at 100 - 300°C and 3 atm;;

in neat (no solvent) between 100 - 350°C under exclusion of water at 3 atm;;

ClSO2F (sulfuryl chloride fluoride) in not given SO2ClF and ClF were condensed onto (SCl)2NAsF6, mixt. was warmed to room temp. with srirring, 5 h; volatiles were removed, products were not isolated; products were analized by IR;

in further solvent(s) Cl2S2 is placed in a FEP-trap (dry-box), evacuated and cooled to -196°C, CFCl3 is condensed into trap, mixt. is warmed to room temp., into this mixt. Fe5SNCl2 is condensed (liquid N2), cooling to -100°C, mixt. is allowed to warm; mixt. is stirred under warming to -20°C for several hours, sepn.by fractional condensation in oil vac. in cold traps at -45, -50, -196°C, react. is followed by Raman-spectroscopy;

in diethyl ether -78°C, among other products;

in diethyl ether -78°C;

byproducts: Cl2, SF4; excess SF5Cl;

carbon monoxide byproducts: S2F10, COS, SO2F2; Irradiation (UV/VIS);