in further solvent(s)
Kinetics; byproducts: C2H5F, (C2H5)2O, OPF2(OC2H5); thermal decomposition of LiPF6 soln. in diethylcarbonate at 85-100 °C for 1-4 weeks; also OPF(OC2H5)2 and C2H4 obtained; detd. by chromy.;
参考文献
Campion, Christopher L.; Li, Wentao; Lucht, Brett L.
Journal of the Electrochemical Society, 2005 , vol. 152, # 12 p. A2327-A2334
in nitric acid
Kinetics; 0.7 wtpercent PF5 soln. in N2O4-HNO3 prepd.; not isoalted; detected by NMR;
参考文献
Addison, C. Clifford; Bailey, John W.; Bruce, Simon H.; Dove, Michael F. A.; Hibbert, Richard C.; Logan, Norman
Polyhedron, 1983 , vol. 2, p. 651 - 656
in nitric acid
6 wtpercent PF5 soln. in N2O4-HNO3 prepd.;
参考文献
Addison, C. Clifford; Bailey, John W.; Bruce, Simon H.; Dove, Michael F. A.; Hibbert, Richard C.; Logan, Norman
Polyhedron, 1983 , vol. 2, p. 651 - 656
byproducts: HCl; HOP(O)F2 droped to C6H4O2PCl3 at -78°C, warmed; ClP(O)F2 condensed on cooling, distilled under vacuum at 41°C/12.0 kPa, distilled fractionally at normal pressure, NMR, elem. anal.;
参考文献
Wolf, Gert-Ulrich; Grunze, Herbert
Zeitschrift fuer Chemie (Stuttgart, Germany), 1982 , vol. 22, # 6 p. 211 - 212
in neat (no solvent)
in NMR tube in presence of excess of HPO2F2 for 3 mo; not isolated, detected by NMR;
参考文献
Dove, Michael F. A.; Hibbert, Richard C.; Logan, Norman
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1984 , p. 2719 - 2722
in nitric acid
19 wtpercent HPO2F2 soln. in HNO3 prepd. at -20°C; not isolated; detected by NMR;
参考文献
Addison, C. Clifford; Bailey, John W.; Bruce, Simon H.; Dove, Michael F. A.; Hibbert, Richard C.; Logan, Norman
Polyhedron, 1983 , vol. 2, p. 651 - 656
in nitric acid
2.7-22.8 wtpercent HPO2F2 soln. in N2O4-HNO3 prepd.; not isolated; detected by NMR;
参考文献
Addison, C. Clifford; Bailey, John W.; Bruce, Simon H.; Dove, Michael F. A.; Hibbert, Richard C.; Logan, Norman
Polyhedron, 1983 , vol. 2, p. 651 - 656
