in neat (no solvent) in NMR tube in presence of excess of HPO2F2 for 3 mo; not isolated, detected by NMR;
参考文献
Dove, Michael F. A.; Hibbert, Richard C.; Logan, Norman
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1984 , p. 2719 - 2722
in nitric acid 19 wtpercent HPO2F2 soln. in HNO3 prepd. at -20°C; not isolated; detected by NMR;
参考文献
Addison, C. Clifford; Bailey, John W.; Bruce, Simon H.; Dove, Michael F. A.; Hibbert, Richard C.; Logan, Norman
Polyhedron, 1983 , vol. 2, p. 651 - 656
in nitric acid 2.7-22.8 wtpercent HPO2F2 soln. in N2O4-HNO3 prepd.; not isolated; detected by NMR;
参考文献
Addison, C. Clifford; Bailey, John W.; Bruce, Simon H.; Dove, Michael F. A.; Hibbert, Richard C.; Logan, Norman
Polyhedron, 1983 , vol. 2, p. 651 - 656
byproducts: HCl; HOP(O)F2 droped to C6H4O2PCl3 at -78°C, warmed; ClP(O)F2 condensed on cooling, distilled under vacuum at 41°C/12.0 kPa, distilled fractionally at normal pressure, NMR, elem. anal.;
Lange, W.; Livingston, R.
Journal of the American Chemical Society, 1950 , vol. 72, p. 1280 - 1281
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Gmelin Handbook: P: MVol.C, 175, page 403 - 404
Lange, W.; Livingstone, R.
Journal of the American Chemical Society, 1947 , vol. 69, p. 1073 - 1076
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Gmelin Handbook: P: MVol.C, 177, page 406 - 409
in not given
react. of anhyd. HF with 100percent H3PO4;;
参考文献
Lange, W.; Livingstone, R.
Journal of the American Chemical Society, 1947 , vol. 69, p. 1073 - 1076
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Gmelin Handbook: P: MVol.C, 177, page 406 - 409
