2-苯基-1,4-环己二烯合成路线 （共 18 条）
反应条件
aluminum oxide; potassium hydroxide; dibromo-difluoro-methane in tetrahydrofuran; tert-butyl alcohol
Ramberg-Baecklund rearrangement;
参考文献
Yao, Qingwei
Organic letters, 2002 , vol. 4, # 3 p. 427 - 430
反应条件
aluminum oxide
T=350°C;
参考文献
Woods et al.
Journal of the American Chemical Society, 1955 , vol. 77, p. 1800
反应条件
in tert-butyl alcohol
Irradiation;
参考文献
Williams,J.L.R. et al.
Journal of the American Chemical Society, 1968 , vol. 90, p. 53 - 55
反应条件
9-bromo-9-borabicyclononane in dichloromethane
T=60°C; 144 h; different dienophiles, reagents and reaction conditions; Product distributionKineticsMechanism;
参考文献
Singleton, Daniel A.; Leung, Shun-Wang; Martinez, Jose P.; Lee, Yu-Kai
Tetrahedron Letters, 1997 , vol. 38, # 18 p. 3163 - 3166
反应条件
1: T=100°C; Diels-Alder reaction; 16 h;
2: With acetic acid in tetrahydrofuran
T=25°C; 2 h;
参考文献
Singleton, Daniel A.; Schulmeier, Brian E.; Hang, Chao; Thomas, Allen A.; Leung, Shun-Wang; Merrigan, Steven R.
Tetrahedron, 2001 , vol. 57, # 24 p. 5149 - 5160
反应条件
1: triphenylphosphine; diisopropyl azodicarboxylate / tetrahydrofuran / 0 °C
2: potassium hydroxide / methanol / 20 °C
3: m-chloroperbenzoic acid / CH2Cl2 / 0 °C
4: 98 percent / (Cy3P)2(Cl)2Ru(=CHPh) / CH2Cl2 / 3.5 h / Heating
5: 78 percent / Br2CF2; KOH/Al2O3 / 2-methyl-propan-2-ol; tetrahydrofuran
View Scheme
参考文献
Yao, Qingwei
Organic letters, 2002 , vol. 4, # 3 p. 427 - 430
反应条件
1: potassium hydroxide / methanol / 20 °C
2: m-chloroperbenzoic acid / CH2Cl2 / 0 °C
3: 98 percent / (Cy3P)2(Cl)2Ru(=CHPh) / CH2Cl2 / 3.5 h / Heating
4: 78 percent / Br2CF2; KOH/Al2O3 / 2-methyl-propan-2-ol; tetrahydrofuran
View Scheme
参考文献
Yao, Qingwei
Organic letters, 2002 , vol. 4, # 3 p. 427 - 430
反应条件
1: 98 percent / (Cy3P)2(Cl)2Ru(=CHPh) / CH2Cl2 / 3.5 h / Heating
2: 78 percent / Br2CF2; KOH/Al2O3 / 2-methyl-propan-2-ol; tetrahydrofuran
View Scheme
参考文献
Yao, Qingwei
Organic letters, 2002 , vol. 4, # 3 p. 427 - 430
反应条件
potassium tert-butylate in tert-butyl alcohol
Heating;
参考文献
Grisdale,P.J. et al.
Journal of Organic Chemistry, 1968 , vol. 33, # 3 p. 1116 - 1119
反应条件
1: (i), (ii) aq. oxalic acid
2: aq. NaOH / ethanol / Heating
3: (i) PhLi, (ii) /BRN= 969135/
4: (pyrolysis)
View Scheme
参考文献
Grisdale,P.J. et al.
Journal of Organic Chemistry, 1968 , vol. 33, # 3 p. 1116 - 1119
