1,1,2,2-四氯-二硼烷合成路线 （共 63 条）
反应条件
compn. of gas phase final product studied by IR spectroscopy;
参考文献
B: B-Verb.9, 2.1.2.1, page 45 - 47
Diss. Abstr., Thesis Pennsylvania State Univ. 1961 , vol. 22, p. 86/7
反应条件
in tetrachloromethane 100°C, 2 weeks; NMR monitoring; not isolated, detected by NMR;
参考文献
Journal of the American Chemical Society, , vol. 104, # 24 p. 6790 - 6791
反应条件
in neat (no solvent) at -48°C;;
参考文献
Journal of the American Chemical Society, , vol. 80, p. 6153 - 6154
Cl: SVol.A, 152, page 355 - 358
N. S. A., CCC-1024-TR-132 (1955) 1/108 , vol. 9, p. 6870
参考文献
Journal of the American Chemical Society, , vol. 71, p. 3265 - 3266
反应条件
highest HBCl2 yield at 15 min;
参考文献
Inorganic Chemistry, , vol. 9, p. 1661,1664
B: B-Verb.9, 1.2.2.1, page 15 - 20
反应条件
in neat (no solvent) reaction carried out in Pyrex tubes to which Teflon valves had been sealed or in a N2-filled glovebox; reaction of B2Cl4 with excess B5H9 in a 1:3 mole ratio; vessel allowed to warm from -196 ° C to ambient temp., 20 min at ambient temp.,; fractionation, yield of 1-BCl2B5H8 based upon amt. of B2Cl4 employed: 73percent, based upon amt. of B5H9 consumed: 95percent; small amts. of B2H6, BCl2H, B2H5Cl, also material insufficiently volatileto move into vac. line formed;;
参考文献
Inorganic Chemistry, , vol. 29, p. 4174 - 4179
反应条件
in neat (no solvent) reaction carried out in pyrex tubes to which Teflon valves had been sealed or N2 filled glovebox; reaction of B2Cl4 with excess B5H9 in a 1.0:1.4 mole ratio; vessel allowed to warm from -196 ° C to ambient temp., 25 min at ambient temp.,; fractionation,;
参考文献
Inorganic Chemistry, , vol. 29, p. 4174 - 4179
反应条件
tetrachloromethane in gas byproducts: HCl, Cl2, C6Cl6; vac. pyrolysis (340 and 420°C, varying molar ratio); fractional condensation, identification by MS and NMR;
参考文献
Journal of Organometallic Chemistry, , vol. 361, p. C54 - C56
反应条件
byproducts: H2; 90°C, excess of H2S, in sealed tube;
参考文献
Journal of the American Chemical Society, , vol. 80, p. 6155 - 6158
S: SVol.4a/b, 1.3.10.1.5, page 262 - 264
反应条件
HCl (liquid) in further solvent(s) reaction of a mixt. of PCl5 and B2Cl4 (2:1) in liquid HCl at -196°C; (11)B and (31)P NMR at 0°C;
参考文献
Zeitschrift fuer Anorganische und Allgemeine Chemie, , vol. 592, p. 35 - 41
