byproducts: GeH2, H2O; passing GeH3Cl through Ag2CO3/glass at 25°C;;
参考文献
Srivastava, T. N.; Griffiths, J. E.; OKnyszchuk, M.
Canadian Journal of Chemistry, 1962 , vol. 40, p. 739 - 744
Full Text Show Details
Gmelin Handbook: Ag: MVol.B3, 16.3.1.8.4, page 291 - 293
Dennis, L. M.; Judy, P. R.
Journal of the American Chemical Society, 1929 , vol. 51, p. 2324 - 2324
Full Text Show Details
Gmelin Handbook: Ge: MVol., 15, page 44 - 46
Dennis, L. M.; Judy, P. R.
Journal of the American Chemical Society, 1929 , vol. 51, p. 2324 - 2324
Full Text Show Details
Gmelin Handbook: Ge: MVol., 15, page 44 - 46
Dennis, L. M.; Judy, P. R.
Journal of the American Chemical Society, 1929 , vol. 51, p. 2324 - 2324
Full Text Show Details
Gmelin Handbook: Ge: MVol., 15, page 44 - 46
AlCl3
congealing of the products; pumping H2 out; fractionating; transition temp.: -135 - -120 °C (GeH4), -120 - -90 °C (HCl), -83 - -78 °C (H3GeCl) and -61 - -52 °C (H2GeCl2);;
参考文献
Dennis, L. M.; Judy, P. R.
Journal of the American Chemical Society, 1929 , vol. 51, p. 2322 - 2322
Full Text Show Details
Gmelin Handbook: Ge: MVol., 15, page 44 - 46
HCl in benzene
under N2, 12 days; detn. by (1)H-NMR;
参考文献
Audett, Judy A. nee Christie; Mackay, Kenneth M.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1988 , p. 2635 - 2644
HCl in benzene
under N2, 2 days; ratio educt: GeMe2HCl : (Fe(CO)4(GeMe2Cl)H) : (Fe(CO)4(GeH3)H) : GeClH3 :(Fe(CO)4(GeClH2)(H) after 2 days 48:20:8:5:8:11;
参考文献
Audett, Judy A. nee Christie; Mackay, Kenneth M.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1988 , p. 2635 - 2644
