byproducts: H2O; passing GeH3Br through Ag2CO3/glass at 25°C or at -28°C, 5 hours;;
参考文献
Srivastava, T. N.; Griffiths, J. E.; OKnyszchuk, M.
Canadian Journal of Chemistry, 1962 , vol. 40, p. 739 - 744
Full Text Show Details
Gmelin Handbook: Ag: MVol.B3, 16.3.1.8.4, page 291 - 293
trimethylamine in neat (no solvent) under N2 or in vac., Me3N : GeH3Br > 1, Me3N condensed onto GeH3Br at -196°C, warmed to -78°C, mixed, then warmed to -63°C; volatile materials removed at -63°C, small quantities of GeH4, Ge2H6 and Ge3H8 (2-8percent);
参考文献
Heil, Charles A.; Norman, Arlan D.
Inorganica Chimica Acta, 1988 , vol. 154, p. 9 - 16
Srivastava, T. N.; Griffiths, J. E.; OKnyszchuk, M.
Canadian Journal of Chemistry, 1962 , vol. 40, p. 739 - 744
Full Text Show Details
Gmelin Handbook: Ag: MVol.B3, 16.8.1.4, page 346 - 349
hydrogen bromide in neat (no solvent)
byproducts: germanes; under N2 or in vac., allowed to warm to -63°C for 1.0 h, treated at -78°C with HBr; traces of germanes;
参考文献
Heil, Charles A.; Norman, Arlan D.
Inorganica Chimica Acta, 1988 , vol. 154, p. 9 - 16
hydrogen bromide in diethylene glycol
byproducts: CH3Br; under N2 or in vac., excess HBr condensed onto soln. of Ge-compd. in diglyme, warmed to 25°C; sepn. by fractional condensation;
参考文献
Heil, Charles A.; Norman, Arlan D.
Inorganica Chimica Acta, 1988 , vol. 154, p. 9 - 16
in neat (no solvent)
byproducts: benzene; HBr condenced onto layer of phenylgermane at liquid N2 temp.; react. mixt sealed in Pyrex vessel and slowly heated overnight to room temp.; resulting mixt. pyrified by trap-to-trap distn. in vac.; gas phase IR;
参考文献
Tackett, Brandon S.; Li, Yunjing; Clouthier, Dennis J.; Pacheco, Kezia L.; Schick, G. Alan; Judge, Richard H.
Journal of Chemical Physics, 2006 , vol. 125, # 11 art. no. 114301
