in neat (no solvent) byproducts: SiBr4; distillation of a solution of I2 and SiBr4 or passing the mixture in a H2 stream to crystalline Si near red heat;;
参考文献
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, , vol. 112, p. 1447 - 1449
in neat (no solvent) The halogen was co-condensed in a flask at -196°C with the mixt. of SiF4 and SiF2 emerging out of the reactor tube;; evapd.,; the volatile products were sepd. and detected by NMR and MS;;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 1123 - 1126
pyridine hydrochloride in chloroform to the soln. of SiI4/CHCl3 the soln. of pyridinium chloride/CHCl3 was added dropwise with stirring, stirred at 298°C under protective gas; gas chromy.;
参考文献
Hass, D.; Bechstein, O.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1981 , vol. 483, p. 140 - 144
pyridine hydrochloride in chloroform to the soln. of SiI4/CHCl3 the soln. of pyridinium chloride/CHCl3 was added dropwise with stirring, stirred at 298°C under protective gas; gas chromy.;
参考文献
Hass, D.; Bechstein, O.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1981 , vol. 483, p. 140 - 144
