in neat (no solvent) passing dry Cl2 through a glass tube, filled with Ca-silicide and heated by a electric spiral at 150-250 °C for about 12-14 days, further products;; fractional distillation;;
参考文献
Si: MVol.B, 242, page 657 - 659
Booth, H. S., Inorganic syntheses, Bd. 1, New York-London 1939, S. 42
byproducts: CH2Cl2; copyrolysis (1:1), quartz tube (550°C, yields of products depending on temperature (350 to 600°C)), product condensing; products not isolated, reaction monitoring by mass spectroscopy;
参考文献
Russian Chemical Bulletin, , vol. 48, # 10 p. 1960 - 1963
in neat (no solvent) The halogen was co-condensed in a flask at -196°C with the mixt. of SiF4 and SiF2 emerging out of the reactor tube; further products;; warmed to room temp.; the volatile products were sepd. and detected by NMR and MS;;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 1123 - 1126
copyrolysis (1percent CHCl3), quartz tube (575°C, retention time 30 s, yields of products depending on temperature (350 to 600°C)), product condensing; products not isolated, reaction monitoring by mass spectroscopy;
参考文献
Russian Chemical Bulletin, , vol. 48, # 10 p. 1960 - 1963
in neat (no solvent) fluorination (N2 carrier gas (ratio F/N2 1:5), -30°C, 2 h);
参考文献
Padma, D K; Kalbandkeri, R G; Suresh, B S; Bhat, V Subrahmanya
Indian Journal of Chemistry, Section A: Inorganic, Bio-inorganic, Physical, Theoretical & Analytical Chemistry, 1991 , vol. 30, # 2 p. 172 - 176
in neat (no solvent) fluorination (N2 carrier gas (ratio F/N2 1:5), -30°C, 2 h);
参考文献
Padma, D K; Kalbandkeri, R G; Suresh, B S; Bhat, V Subrahmanya
Indian Journal of Chemistry, Section A: Inorganic, Bio-inorganic, Physical, Theoretical & Analytical Chemistry, 1991 , vol. 30, # 2 p. 172 - 176
in neat (no solvent) byproducts: (t-C4H9)(i-C3H7)PSiCl3, (t-C4H9)(i-C3H7)PSi2Cl5; N2 atmosphere, addn. of Si2Cl6 to ice-cooled stannyl compound, warming to room temp., 5 min; variation of reaction time; (119)Sn- and (31)P-NMR-monitoring;
参考文献
European Journal of Inorganic Chemistry, , # 8 p. 1381 - 1392
in neat (no solvent) byproducts: (t-C4H9)(i-C3H7)PSiCl3, (t-C4H9)(i-C3H7)PSi2Cl5; N2 atmosphere, addn. of Si2Cl6 to ice-cooled stannyl compound, warming to room temp., 60 min; variation of reaction time; (119)Sn- and (31)P-NMR-monitoring;
参考文献
European Journal of Inorganic Chemistry, , # 8 p. 1381 - 1392
Forbes, G. S.; Anderson, H. H.
Journal of the American Chemical Society, 1944 , vol. 66, p. 1703 - 1703
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Gmelin Handbook: Si: MVol.B, 325, page 859 - 861
