in neat (no solvent) chlorination of crude Si at 300-310 °C; best yield of SiCl4;;
参考文献
Gattermann, L.; Ellery, E.
Ber., 1899 , vol. 32, p. 1114 - 1116
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Gattermann, L.; Weinlig, K.
Ber., 1894 , vol. 27, p. 1943 - 1948
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Gmelin Handbook: Si: MVol.B, 242, page 657 - 659
in neat (no solvent) dropwise addn. of a mixture of Si3Cl8 and Br2 into a glass tube heated at 500°C under passing CO2 through the tube; reaction with inflammation;;
参考文献
Journal of the American Chemical Society, , vol. 59, p. 651 - 653
Na(Si-t-Bu3) in benzene byproducts: (t-Bu3Si)4Si, t-Bu3SiSi-t-Bu3, t-Bu3SiCl; under N2 or Ar; soln. of Cl3SiSiCl2SiCl3 and Na(Si-t-Bu3) (molar ratio 1:4) in benzene stirred at ambient temp. for 1 d; detd. by (29)Si NMR spectra;
