in neat (no solvent) under inert atmosphere; eqimolar amt. of SiCl4 and SiBr4 equilibrated by stirring at room temp. for 3 d; sepd. by repeated fractional distn. at ambient pressure; immediately frozen; characterized by (29)Si NMR;
参考文献
Hcnsen, Karl; Mayr-Stein, Ralf; Stumpf, Thorsten; Pickel, Peter; Boite, Michael; Fleischer, Holger
Journal of the Chemical Society, Dalton Transactions, 2000 , # 4 p. 473 - 477
in neat (no solvent) heating of a mixture of SiBr4 and PCl3 (1:1) for a period of 1 hour;; mixture obtained;;
参考文献
Schumb, W. C.; Anderson, H. H.
Journal of the American Chemical Society, 1937 , vol. 59, p. 651 - 653
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Gmelin Handbook: Si: MVol.B, 272, page 732 - 735
in neat (no solvent) dropwise addn. of a mixture of Si2Cl6 and Br2 into a glass tube heated at 500°C under passing CO2 through the tube; reaction with inflammation;; condensation under cooling with ice; shaking with Hg; mixture obtained;;
参考文献
Schumb, W. C.; Anderson, H. H.
Journal of the American Chemical Society, 1937 , vol. 59, p. 651 - 653
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Gmelin Handbook: Si: MVol.B, 272, page 732 - 735
in neat (no solvent) heating SiBr4 in Cl2 atmosphere under reflux;; mixture obtained;;
参考文献
Schumb, W. C.; Anderson, H. H.
Journal of the American Chemical Society, 1937 , vol. 59, p. 651 - 653
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Gmelin Handbook: Si: MVol.B, 272, page 732 - 735
in neat (no solvent) passing a mixture of Cl2 and Br2 over metallic Si at 700°C;; fractional distillation;;
参考文献
Schumb, W. C.; Anderson, H. H.
Journal of the American Chemical Society, 1937 , vol. 59, p. 651 - 653
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Gmelin Handbook: Si: MVol.B, 272, page 732 - 735
in neat (no solvent) dropwise addn. of a mixture of Si3Cl8 and Br2 into a glass tube heated at 500°C under passing CO2 through the tube; reaction with inflammation;;
参考文献
Schumb, W. C.; Anderson, H. H.
Journal of the American Chemical Society, 1937 , vol. 59, p. 651 - 653
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Gmelin Handbook: Si: MVol.B, 272, page 732 - 735
pyridine hydrochloride in chloroform to the soln. of SiBr4/CHCl3 the soln. of pyridinium chloride/CHCl3 was added dropwise with stirring, stirred at 298°C under protective gas; gas chromy.;
参考文献
Hass, D.; Bechstein, O.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1981 , vol. 483, p. 140 - 144
