in neat (no solvent)
inert atmosphere (N2, Ar or high vac.), room temperature, equimolar amts. of halosilane/tinhydride, reactn. time 6-8 h; not isolated; IR spectroscopy (identified 95percent SiF3H, trace SiF2H2 and trace SiH4 in product mixt.);
参考文献
D'Errico, John J.; Sharp, Kenneth G.
Inorganic Chemistry, 1989 , vol. 28, p. 2177 - 2180
in neat (no solvent)
inert atmosphere (N2, Ar or high vac.), room temperature, equimolar amts. of halosilane/tinhydride, reactn. time 60 h; not isolated; IR spectroscopy (identified 95percent SiF3H, trace SiF2H2 and trace SiH4 in product mixt.);
参考文献
D'Errico, John J.; Sharp, Kenneth G.
Inorganic Chemistry, 1989 , vol. 28, p. 2177 - 2180
in neat (no solvent)
inert atmosphere (N2, Ar or high vac.), room temperature, equimolar amts. of halosilane/tinhydride, reactn. time 6-8 h; not isolated; IR spectroscopy (identified 95percent SiF3H, trace SiF2H2 and trace SiH4 in product mixt.);
参考文献
D'Errico, John J.; Sharp, Kenneth G.
Inorganic Chemistry, 1989 , vol. 28, p. 2177 - 2180
in neat (no solvent)
inert atmosphere (N2, Ar or high vac.), room temp., equimolar amts. of halosilane/tinhydride, reactn. time 6-8 h; not isolated; IR spectroscopy (identified 95percent SiF3H, trace SiF2H2 and trace SiH4 in product mixt.);
参考文献
D'Errico, John J.; Sharp, Kenneth G.
Inorganic Chemistry, 1989 , vol. 28, p. 2177 - 2180
in neat (no solvent)
equimolar amts. of Me3SnH and SiF2Cl2 room temp., 3.5 days; removing of Me3SnBr by trap coolingto -131°C, cooling to -196°C; not isolated; IR, (1)H-, (19)F-NMR spectroscopy (identified 5percent SiF3H, 5percent SiH4 and 5percent SiFCl2H in product mixt.);
参考文献
D'Errico, John J.; Sharp, Kenneth G.
Inorganic Chemistry, 1989 , vol. 28, p. 2177 - 2180
in neat (no solvent)
repeated passage of HSiCl3 over SbF5 (0°C); distn. (condensing at -95°C, toluene slush bath);
参考文献
Archer, Nicholas J.; Haszeldine, Robert N.; Parish, R. V. (Dick)
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1979 , p. 695 - 702
in not given
SbF3 was dropped into liquid SiHCl3 containing SbCl5; Purification by trap to trap distillation;
参考文献
Arthur, Neville L.; Potzinger, Peter; Reimann, Bruno; Steenbergen, H. Peter
Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1989 , vol. 85, p. 1447 - 1464
in neat (no solvent)
N2 atmosphere, high vac. line; condensing (molar ratio SnMe3H:Si2HF5:C2F4 1:1:3), warming (room temp., 1.5 h); passing through traps (-78°C and -46°C);
参考文献
D'Errico, John; Sharp, Kenneth G.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1989 , p. 1879 - 1882
