in dichloromethane byproducts: (CH3)3SiF; (Ar, Schlenk) a soln. of SeF4 in CH2Cl2 was treated with (CH3)3SiCN at -50°C dropwise, stired for 15 min; not sepd., detected by spectra;
参考文献
Klapoetke, Thomas M.; Krumm, Burkhard; Scherr, Matthias
Inorganic Chemistry, 2008 , vol. 47, # 15 p. 7025 - 7028
Prideaux, E. B. R.; Cox, C. B.
Journal of the Chemical Society, 1928 , p. 1606 - 1606
Full Text Show Details
Gmelin Handbook: Se: MVol.B, 50, page 111 - 113
Gmelin Handbook: P: MVol.B, 3.4.2.2, page 307 - 310
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Prideaux, E. B. R.; Cox, C. B.
Journal of the Chemical Society, 1928 , p. 1603 - 1607
in diethyl ether reaction of SeF4 with a solution of BiBr3 (10 percent) in ether with precipitation of BiF3 and formation of an orange yellow solution of SeBr4 in ether;;
in diethyl ether reaction of SeF4 with a solution of BiBr3 (10 percent) in ether with precipitation of BiF3 and formation of an orange yellow solution of SeBr4 in ether;;
