water in water
MoO3 and RbIO4 were loaded in Parr 4749 PTFE-lined autoclave, water was added, the mixt. was heated for 3 d at 180°C; the autoclave was cooled at a rate of 9°C/h to 23°C, the mother liquors were decanted from crystalline products that were subsequently washed with methanol, the colorless plates of RbMoO3(IO3) were sepd. from colorless cubes of RbIO3;
参考文献
Sykora, Richard E.; Kang, Min Ok; Halasyamani, P. Shiv; Albrecht-Schmitt, Thomas E.
Journal of the American Chemical Society, 2002 , vol. 124, # 9 p. 1951 - 1957
in water
addn. of I2O5 to an aq. soln. of Rb2CO3 (equimolar amounts);;
参考文献
Wheeler, H. L.
Am. J. Sci., 1892 , vol. 44, p. 125 - 125
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Wheeler, H. L.
Z. Anorg. Chem., 1892 , vol. 2, p. 438 - 438
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反应条件
in water
High Pressure; under hydrothermal conditions; mixt. of Rb2CO3, In2O3 and H5IO6 in H2O sealed in autoclave; heated at 200°C for 4 d; cooled slowly to room temp. (6°C/h); initial and final pH are 0.6 and 0.7; satisfactory elem. anal.;