2,4,4-三甲基-2-环己烯-1-酮合成路线 （共 20 条）
参考文献
Bougault
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1910 , vol. 150, p. 397
反应条件
potassium hydroxide; hydrogen; RuCl2lt;(S)-binapgt;(dmf)n*(R,R)-1,2-diphenylethylenediamine in isopropyl alcohol T=28°C; P=6080 Torr; 12 h; Yields of byproduct given;
参考文献
Synlett, , # SPEC. ISS. p. 467 - 468
反应条件
sodium tetrahydroborate; cerium(III) chloride in methanol T=0 - 6°C; 0.166667 h;
参考文献
Mori, Kenji; Puapoomchareon, Prapai
Liebigs Annalen der Chemie, 1991 , # 10 p. 1053 - 1056
反应条件
1: 2,4,4-trimethylcyclohex-2-en-1-one With ammonia; lithium in diethyl ether; water T=-78 - 20°C; 2: methyl iodide in diethyl ether; water; tert-butyl alcohol T=-78°C; 1 h; Reflux;
参考文献
Journal of Medicinal Chemistry, , vol. 55, # 10 p. 4837 - 4846
反应条件
D-glucose; Yamadazyma farinosa IFO 10896 in phosphate buffer
T=30°C; pH=6.5; 4 h; Title compound not separated from byproducts.;
参考文献
Matsumoto, Kazutsugu; Kawabata, Yoichi; Okada, Satoshi; Takahashi, Jun; Hashimoto, Key; Nagai, Yuto; Tatsuta, Junichi; Hatanaka, Minoru
Chemistry Letters, 2007 , vol. 36, # 12 p. 1428 - 1429
反应条件
Catalyst M-Chromium oxide; sulfuric acid
参考文献
Bougault
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1910 , vol. 150, p. 397
反应条件
sulfuric acid
1) < 50 deg C, 5 h; 2) reflux, 12 h;
参考文献
Paquette, Leo A.; Oplinger, Jeffrey A.
Tetrahedron, 1989 , vol. 45, # 1 p. 107 - 124
反应条件
1: N2H4*H2O, KOH / bis-(2-hydroxy-ethyl) ether
2: SeO2
3: KOH / ethanol
4: CrO3, aq. AcOH / bis-(2-hydroxy-ethyl) ether
View Scheme
参考文献
Alkonyi,I.
Chemische Berichte, 1961 , vol. 94, p. 2486 - 2489
反应条件
1: SeO2
2: KOH / ethanol
3: CrO3, aq. AcOH / bis-(2-hydroxy-ethyl) ether
View Scheme
参考文献
Alkonyi,I.
Chemische Berichte, 1961 , vol. 94, p. 2486 - 2489
反应条件
1: KOH / ethanol
2: CrO3, aq. AcOH / bis-(2-hydroxy-ethyl) ether
View Scheme
参考文献
Alkonyi,I.
Chemische Berichte, 1961 , vol. 94, p. 2486 - 2489
