5,9-甲桥-6,7,8,9-四氢-7H-苯并环庚烯-7-酮合成路线 （共 14 条）
反应条件
1: sodium borohydride / ethanol / 20 h / Ambient temperature 2: 17 percent / CCl4, triphenylphosphine / 16 h / Heating View Scheme
参考文献
Morrison, Harry; Muthuramu, Kayambu; Severance, Daniel
Journal of Organic Chemistry, 1986 , vol. 51, # 24 p. 4681 - 4687
反应条件
potassium hydroxide; hydrazine hydrate
参考文献
Wilt,J.W. et al.
Journal of Organic Chemistry, 1970 , vol. 35, # 7 p. 2402 - 2410
反应条件
1: 81 percent / hydroxylamine hydrochloride, sodium acetate trihydrate / H2O; methanol / 0.17 h / Heating
2: 95 percent / polyphosphoric acid / 0.5 h / 100 - 120 °C
3: 96 percent / 1M borane-tetrahydrofuran complex / tetrahydrofuran / 15 h / Heating
View Scheme
参考文献
Mazzocchi; Kordoski; Rosenthal
Journal of Heterocyclic Chemistry, 1982 , vol. 19, # 4 p. 941 - 942
反应条件
1: 81 percent / hydroxylamine hydrochloride, sodium acetate trihydrate / H2O; methanol / 0.17 h / Heating
2: 95 percent / polyphosphoric acid / 0.5 h / 100 - 120 °C
View Scheme
参考文献
Mazzocchi; Kordoski; Rosenthal
Journal of Heterocyclic Chemistry, 1982 , vol. 19, # 4 p. 941 - 942
