4-(三甲基硅氧基)-3-戊烯-2-酮合成路线 （共 26 条）
反应条件
in nitromethane 0.5 h; Ambient temperature;
参考文献
Stahl, Ingfried
Chemische Berichte, 1985 , vol. 118, # 12 p. 4857 - 4868
反应条件
in nitromethane 0.5 h; Ambient temperature;
参考文献
Stahl, Ingfried
Chemische Berichte, 1985 , vol. 118, # 12 p. 4857 - 4868
反应条件
in nitromethane 1.5 h; Ambient temperature;
参考文献
Stahl, Ingfried
Chemische Berichte, 1985 , vol. 118, # 12 p. 4857 - 4868
反应条件
in nitromethane 2 h; Ambient temperature;
参考文献
Stahl, Ingfried
Chemische Berichte, 1985 , vol. 118, # 12 p. 4857 - 4868
反应条件
in nitromethane; dichloromethane 2 h; -70 deg C to r.t.;
参考文献
Stahl, Ingfried
Chemische Berichte, 1985 , vol. 118, # 12 p. 4857 - 4868
反应条件
zinc in ethanol under inert atm. soln. Ru complex and Zn dust in EtOH were stirred at room temp. for 5 min, 4-trimethylsiloxy-3-penten-2-one was added and stirred for 22 h; ppt. was filtered, dissolved in toluene and concd., hexane was added, recrystn. from CH2Cl2-hexane at -78°C - (Cp*Ru(C6H5Me))Cl, filtratewas evapd., extd. with toluene and chromed. on alumina - (Ru(acac)3);
参考文献
Organometallics, , vol. 27, # 23 p. 6071 - 6082
反应条件
T=800°C; P=0.1 Torr; 2.77778E-07 h; quartz tube; Yields of byproduct given;
参考文献
Tetrahedron, , vol. 38, # 10 p. 1413 - 1416
反应条件
in nitromethane; dichloromethane 2 h; -70 deg C to r.t.;
参考文献
Stahl, Ingfried
Chemische Berichte, 1985 , vol. 118, # 12 p. 4857 - 4868
反应条件
zinc in ethanol under inert atm. soln. Ru complex and Zn dust in EtOH were stirred at room temp. for 5 min, 4-trimethylsiloxy-3-penten-2-one was added and stirred for 22 h; ppt. was filtered, dissolved in toluene and concd., hexane was added, recrystn. from CH2Cl2-hexane at -78°C - (Cp*Ru(C6H5Me))Cl, filtratewas evapd., extd. with toluene and chromed. on alumina - (Ru(acac)3);
参考文献
Organometallics, , vol. 27, # 23 p. 6071 - 6082
反应条件
triethyl borane 1.) heptane, 30 min, 2.) 2 min, room temp.; Yield given. Multistep reaction;
参考文献
Taba, Kalulu M.; Dahlhoff, Wilhelm Volker
Synthesis, 1982 , # 8 p. 652 - 653
