(三甲基硅基)甲基氯化镁合成路线 （共 130 条）
反应条件
in not given (CH3)3SiCH2MgCl and CO2; acidic hydrolysis;;
参考文献
Sommer et al.
Journal of the American Chemical Society, 1949 , vol. 71, p. 1509
反应条件
hydrogenchloride in not given (CH3)3SiCH2MgCl and ethylene oxide; hydrolysis with HCl;;
参考文献
Sommer; Van Strien; Whitmore
Journal of the American Chemical Society, 1949 , vol. 71, p. 3056
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Speier, J. L.
Journal of the American Chemical Society, 1952 , vol. 74, p. 1003 - 1010
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Gmelin Handbook: Si: MVol.C, 9, page 28 - 32
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Dow Corning Corp.
Patent: US2557802 , 1951 ;
C. A., 1952 , p. 1026
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Dow Corning Corp.
Patent: US2629727 , 1953 ;
C. A., 1954 , p. 1418
反应条件
cesium fluoride 1.) Et2O, 35 deg C, 2 h, 2.) DMSO, 130 deg C, 3 h; Yield given. Multistep reaction;
参考文献
Sakurai, Hideki; Hosomi, Akira; Saito, Masaki; Sasaki, Koshi; Iguchi, Hirokazu; et al.
Tetrahedron, 1983 , vol. 39, # 6 p. 883 - 894
反应条件
thionyl chloride 1.) ether, 3 h, 2.) ether, 2 h, room temp.,; Yield given. Multistep reaction;
参考文献
Haider, Akhtar
Synthesis, 1985 , # 3 p. 271 - 272
反应条件
in diethyl ether 0.5 h; Ambient temperature;
参考文献
Hayashi; Matsumoto; Ito
Tetrahedron Asymmetry, 1991 , vol. 2, # 7 p. 601 - 612
反应条件
bis(acetylacetonate)nickel(II) in diethyl ether 15 h; Ambient temperature;
参考文献
Hayashi, Tamio; Katsuro, Yoshio; Okamoto, Yasuo; Kumada, Makoto
Tetrahedron Letters, 1981 , vol. 22, # 44 p. 4449 - 4452
反应条件
bis(acetylacetonate)nickel(II) in diethyl ether 15 h; Ambient temperatureOther catalysts; Product distribution;
参考文献
Hayashi, Tamio; Katsuro, Yoshio; Okamoto, Yasuo; Kumada, Makoto
Tetrahedron Letters, 1981 , vol. 22, # 44 p. 4449 - 4452
参考文献
Petrov, A. D.; Nikishin, G. I.
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1952 , p. 1128 - 1130
C. A., 1954 , p. 1247
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Gmelin Handbook: Si: MVol.C, 16, page 48 - 53
反应条件
sec-butylmagnesium chloride; copper(l) chloride in diethyl ether 1) -20 deg C, 2) RT, 3d;
参考文献
Trost; Matelich
Synthesis, 1992 , # 1-2 p. 151 - 156
反应条件
lithium aluminium tetrahydride; arsenic(III) chloride 1.) ether, pentane, -78 deg to room temperature, 2.) THF; Multistep reaction;
参考文献
Wells, Richard L.; Purdy, Andrew P.; Pitt, Colin G.
Phosphorus, Sulfur and Silicon and the Related Elements, 1991 , vol. 57, # 1/2 p. 1 - 3
