carbon monoxide; water in tetrahydrofuran byproducts: S(CH3)2; a soln. of BH3*S(CH3)2 flushed with CO; a soln. of catalyst added, stirred rapidly and maintained at 25°C for 12-16 h; water added; evapd.;
参考文献
Brown, Herbert C.; Cole, Thomas E.
Organometallics, 1985 , vol. 4, p. 816 - 821
hydrogenchloride in diethyl ether byproducts: LiCl, i-propanol; (N2); a soln. of B(O-i-Pr)3 cooled with a dry ice-acetone bath; CH3Li added slowly and stirred for 1 h; allowed to warm to room temp. with stirring for 3 h; cooled to 0°C; a soln. of HCl in ether added and stirred for 0.5 h; decanted; hydrolyzed with water; distd.; dried;
参考文献
Brown, Herbert C.; Cole, Thomas E.
Organometallics, 1985 , vol. 4, p. 816 - 821
