3,7-二硝基-5-(三氟甲基)二苯并[b,d]噻吩鎓三氟甲烷磺酸酯合成路线 （共 13 条）
反应条件
nitronium trifluoromethanesulfonate 72 h; Ambient temperature;
参考文献
Umemoto, Teruo; Ishihara, Sumi
Journal of the American Chemical Society, 1993 , vol. 115, # 6 p. 2156 - 2164
反应条件
1: 83 percent / F2 / CCl3F / 0 °C 2: 85 percent / TfONO2 / 72 h / Ambient temperature View Scheme
参考文献
Umemoto, Teruo; Ishihara, Sumi
Journal of the American Chemical Society, 1993 , vol. 115, # 6 p. 2156 - 2164
反应条件
1: 1.) NaH / 1.) DMF, 2.) DMF, irradiation, 2 h 2: 83 percent / F2 / CCl3F / 0 °C 3: 85 percent / TfONO2 / 72 h / Ambient temperature View Scheme
参考文献
Umemoto, Teruo; Ishihara, Sumi
Journal of the American Chemical Society, 1993 , vol. 115, # 6 p. 2156 - 2164
反应条件
1: 75 percent / 1,1,2-trichloro-1,2,2-trifluoro-ethane / 2 h / Ambient temperature 2: 85 percent / TfONO2 / 72 h / Ambient temperature View Scheme
参考文献
Umemoto; Ishihara
Tetrahedron Letters, 1990 , vol. 31, # 25 p. 3579 - 3582
反应条件
1: CCl3F / 1 h / -78 - 20 °C 2: 85 percent / TfONO2 / 72 h / Ambient temperature View Scheme
参考文献
Umemoto, Teruo; Ishihara, Sumi
Journal of the American Chemical Society, 1993 , vol. 115, # 6 p. 2156 - 2164
反应条件
1: 88 percent / dimethylformamide / 0 °C / Irradiation 2: 98 percent / m-chloroperbenzoic acid 3: 75 percent / 1,1,2-trichloro-1,2,2-trifluoro-ethane / 48 h / Ambient temperature 4: triflic anhydride, nitric acid / r.t., 3d View Scheme
参考文献
Umemoto; Ishihara
Tetrahedron Letters, 1990 , vol. 31, # 25 p. 3579 - 3582
反应条件
in N,N-dimethyl-formamide 2 h; Ambient temperature; Title compound not separated from byproducts;
参考文献
Umemoto; Ishihara
Tetrahedron Letters, 1990 , vol. 31, # 25 p. 3579 - 3582
反应条件
in DMF-d7 T=-10°C; other temperatures and solvents; ΔH(excit.), ΔS(excit.), ΔG(excit.); KineticsThermodynamic data;
参考文献
Ono, Taizo; Umemoto, Teruo
Journal of Fluorine Chemistry, 1996 , vol. 80, # 2 p. 163 - 166
参考文献
Umemoto, Teruo; Adachi, Kenji; Ishihara, Sumi
Journal of Organic Chemistry, 2007 , vol. 72, # 18 p. 6905 - 6917
参考文献
Umemoto, Teruo; Adachi, Kenji; Ishihara, Sumi
Journal of Organic Chemistry, 2007 , vol. 72, # 18 p. 6905 - 6917
