P(C6H5)2CH3 in benzene byproducts: P(C6H5)2CH3; to a solution of the Zr-complex and the phosphine in C6H6 was added 6-chloro-1-hexene; stirred 45 min; room temperature; NMR;
参考文献
Journal of the American Chemical Society, , vol. 102, # 10 p. 3660 - 3662
in not given extn. using pentane, sublimation; not isolated;
参考文献
Lee, Bun Yeoul; Wang, Shujun; Putzer, Markus; Bartholomew, Glenn P.; Bu, Xianhui; Bazan, Guillermo C.
Journal of the American Chemical Society, 2000 , vol. 122, # 16 p. 3969 - 3970
in diethyl ether on standard vac. line; Et2O condensed at -78°C onto Zr complex; cooled to -196°C; HCl gas (1 equiv.) condensed onto frozen mass; warmed to -55°C; stirred for 90 min; volatiles removed in vac. at -55°C; coolected at -196°C over 18 h; detd. by (1)H, (13)C and (11)B NMR spectroscopy;
参考文献
Thomas, Rhodri Ll.; Rath, Nigam P.; Barton, Lawrence
Inorganic Chemistry, 2002 , vol. 41, # 1 p. 67 - 75
in benzene treatment of the Zr compd. in benzene suspn. with SbCl3 (1 equiv) (25°C), removal of solvent (vac.); extn. (hexane/ether (10:1)), chromy. (anhyd. MgSO4);
参考文献
Buchwald, Stephen L.; Fisher, Richard A.; Davis, William M.
Organometallics, 1989 , vol. 8, p. 2082 - 2084
in benzene treatment of the Zr compd. in benzene suspn. with SbCl3 (1 equiv) (25°C), removal of solvent (vac.); extn. (hexane/ether (10:1)), chromy. (anhyd. MgSO4);
参考文献
Buchwald, Stephen L.; Fisher, Richard A.; Davis, William M.
Organometallics, 1989 , vol. 8, p. 2082 - 2084
in benzene treatment of the Zr compd. in benzene suspn. with SbCl2Br (1 equiv) (25°C), removal of solvent (vac.); extn. (hexane/ether (10:1)), chromy. (anhyd. MgSO4);
参考文献
Buchwald, Stephen L.; Fisher, Richard A.; Davis, William M.
Organometallics, 1989 , vol. 8, p. 2082 - 2084
in benzene treatment of the Zr compd. in benzene suspn. with PhSbCl2 (1 equiv) (25°C), removal of solvent (vac.); extn. (hexane/ether (10:1)), chromy. (alumina III);
参考文献
Buchwald, Stephen L.; Fisher, Richard A.; Davis, William M.
Organometallics, 1989 , vol. 8, p. 2082 - 2084
in tetrahydrofuran under Ar atm. SbCl3 was added to soln. 1,1-bis(cyclopentadienyl)-2,3,4,5-tetraethyl-1-zirconacyclopenta-2,4-diene in THF and stirred for 24 h at room temp.; volatile materials were removed under vac., residue was extd. with pentane, solvent was removed; elem. anal.;
参考文献
Westerhausen, Matthias; Gueckel, Christian; Warchhold, Marcus; Noeth, Heinrich
Organometallics, 2000 , vol. 19, # 12 p. 2393 - 2396
