1: 23 percent / SnCl4 / CH2Cl2 / 2 h / Ambient temperature 2: 96 percent / LiAlH4, AlCl3 / diethyl ether / 1 h / Heating 3: 75 percent / iodine / toluene / 48 h / Heating 4: 8 percent / Nafion-H / toluene / 24 h / Heating View Scheme

1: 75 percent / iodine / toluene / 48 h / Heating 2: 8 percent / Nafion-H / toluene / 24 h / Heating View Scheme

1: 96 percent / LiAlH4, AlCl3 / diethyl ether / 1 h / Heating 2: 75 percent / iodine / toluene / 48 h / Heating 3: 8 percent / Nafion-H / toluene / 24 h / Heating View Scheme

in various solvent(s) T=399.85°C; Condensation; Formation of xenobiotics;

1.1: AlCl3, aluminium chloride / tetrachloroethane, 1,1,2,2- / 20 °C / Cooling with ice 2.1: hydrazine hydrate / diethylene glycol / 0.5 h / 20 °C 2.2: 120 - 215 °C 3.1: sulfuric acid / Reflux 4.1: palladium 10 on activated carbon / triglyme (triethylene glycol dimethyl ether) / 4 h / 240 °C / Inert atmosphere 5.1: methanesulfonic acid / 0.5 h / 90 °C / Inert atmosphere 6.1: n-butyllithium; N-cyclohexyl-N-isopropylamine / tetrahydrofuran; hexane / -78 °C / Inert atmosphere 6.2: 1 h / -78 °C / Inert atmosphere 7.1: palladium 10 on activated carbon / triglyme (triethylene glycol dimethyl ether) / 4 h / 240 °C / Inert atmosphere 8.1: diisobutylaluminium hydride / hexane; toluene / 1 h / -78 °C / Inert atmosphere 8.2: Inert atmosphere 9.1: methanesulfonic acid / dichloromethane / 0.5 h / 20 °C / Cooling with ice View Scheme

1.1: n-butyllithium; N-cyclohexyl-N-isopropylamine / tetrahydrofuran; hexane / -78 °C / Inert atmosphere 1.2: 1 h / -78 °C / Inert atmosphere 2.1: palladium 10 on activated carbon / triglyme (triethylene glycol dimethyl ether) / 4 h / 240 °C / Inert atmosphere 3.1: diisobutylaluminium hydride / hexane; toluene / 1 h / -78 °C / Inert atmosphere 3.2: Inert atmosphere 4.1: methanesulfonic acid / dichloromethane / 0.5 h / 20 °C / Cooling with ice View Scheme

1.1: methanesulfonic acid / 0.5 h / 90 °C / Inert atmosphere 2.1: n-butyllithium; N-cyclohexyl-N-isopropylamine / tetrahydrofuran; hexane / -78 °C / Inert atmosphere 2.2: 1 h / -78 °C / Inert atmosphere 3.1: palladium 10 on activated carbon / triglyme (triethylene glycol dimethyl ether) / 4 h / 240 °C / Inert atmosphere 4.1: diisobutylaluminium hydride / hexane; toluene / 1 h / -78 °C / Inert atmosphere 4.2: Inert atmosphere 5.1: methanesulfonic acid / dichloromethane / 0.5 h / 20 °C / Cooling with ice View Scheme

1.1: palladium 10 on activated carbon / triglyme (triethylene glycol dimethyl ether) / 4 h / 240 °C / Inert atmosphere 2.1: methanesulfonic acid / 0.5 h / 90 °C / Inert atmosphere 3.1: n-butyllithium; N-cyclohexyl-N-isopropylamine / tetrahydrofuran; hexane / -78 °C / Inert atmosphere 3.2: 1 h / -78 °C / Inert atmosphere 4.1: palladium 10 on activated carbon / triglyme (triethylene glycol dimethyl ether) / 4 h / 240 °C / Inert atmosphere 5.1: diisobutylaluminium hydride / hexane; toluene / 1 h / -78 °C / Inert atmosphere 5.2: Inert atmosphere 6.1: methanesulfonic acid / dichloromethane / 0.5 h / 20 °C / Cooling with ice View Scheme

1.1: sulfuric acid / Reflux 2.1: palladium 10 on activated carbon / triglyme (triethylene glycol dimethyl ether) / 4 h / 240 °C / Inert atmosphere 3.1: methanesulfonic acid / 0.5 h / 90 °C / Inert atmosphere 4.1: n-butyllithium; N-cyclohexyl-N-isopropylamine / tetrahydrofuran; hexane / -78 °C / Inert atmosphere 4.2: 1 h / -78 °C / Inert atmosphere 5.1: palladium 10 on activated carbon / triglyme (triethylene glycol dimethyl ether) / 4 h / 240 °C / Inert atmosphere 6.1: diisobutylaluminium hydride / hexane; toluene / 1 h / -78 °C / Inert atmosphere 6.2: Inert atmosphere 7.1: methanesulfonic acid / dichloromethane / 0.5 h / 20 °C / Cooling with ice View Scheme

1.1: hydrazine hydrate / diethylene glycol / 0.5 h / 20 °C 1.2: 120 - 215 °C 2.1: AlCl3, aluminium chloride / tetrachloroethane, 1,1,2,2- / 20 °C / Cooling with ice 3.1: hydrazine hydrate / diethylene glycol / 0.5 h / 20 °C 3.2: 120 - 215 °C 4.1: sulfuric acid / Reflux 5.1: palladium 10 on activated carbon / triglyme (triethylene glycol dimethyl ether) / 4 h / 240 °C / Inert atmosphere 6.1: methanesulfonic acid / 0.5 h / 90 °C / Inert atmosphere 7.1: n-butyllithium; N-cyclohexyl-N-isopropylamine / tetrahydrofuran; hexane / -78 °C / Inert atmosphere 7.2: 1 h / -78 °C / Inert atmosphere 8.1: palladium 10 on activated carbon / triglyme (triethylene glycol dimethyl ether) / 4 h / 240 °C / Inert atmosphere 9.1: diisobutylaluminium hydride / hexane; toluene / 1 h / -78 °C / Inert atmosphere 9.2: Inert atmosphere 10.1: methanesulfonic acid / dichloromethane / 0.5 h / 20 °C / Cooling with ice View Scheme