in n-heptane byproducts: P2Ph4; absence of air and moisture; equimolar amts., room temp., 30 min; crystn. (12 h), dissoln. of P2Ph4 by heating, filtration; elem. anal.;
参考文献
Fachinetti, Giuseppe; Floriani, Carlo; Stoeckli-Evans, Helen
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1977 , p. 2297 - 2302
hydrogenchloride in water; acetone byproducts: CH4; thermochemical measurements were carried out; confirmed by IR spectroscopic analysis;
参考文献
Calhorda, Maria J.; Dias, Alberto R.; Minas da Piedade, Manuel E.; Salema, Margarida S.; Simoes, Jose A. Martinho
Organometallics, 1987 , vol. 6, p. 734 - 738
hydrogenchloride in water; acetone byproducts: CH4; thermochemical measurements were carried out; confirmed by IR spectroscopic analysis;
参考文献
Calhorda, Maria J.; Dias, Alberto R.; Minas da Piedade, Manuel E.; Salema, Margarida S.; Simoes, Jose A. Martinho
Organometallics, 1987 , vol. 6, p. 734 - 738
in benzene (exclusion of moisture), ligand and Ti complex stirred in benzene at 30-40°C for 150 min; evapd.(vac.), dissolved (CS2), treated with n-pentane, cooled to -26°C, isolated, washed (n-pentane), dried (air), elem. anal.;
参考文献
European Journal of Inorganic Chemistry, , # 4 p. 718 - 725
in benzene-d6 Irradiation (UV/VIS); (N2 or Ar); complex and (C6H5)3CCl soln. irradiated (313 nm) at room temp. with stirring for 4 h; not isolated, detected by NMR;
参考文献
Journal of the American Chemical Society, , vol. 106, # 22 p. 6660 - 6664
in dichloromethane dropping of solns. of Ti-complex and of S2Cl2 to CH2Cl2 (stirring, room temp., over period of 6 h), pptn., filtration, washing (CH2Cl2); filtration of CH2Cl2 sol. portion (silica gel), pptn. on concn.; elem. anal.;
参考文献
Journal of the American Chemical Society, , vol. 111, # 9 p. 3465 - 3466
in diethyl ether C5H4(CH3)Li slurry added slowly to TiCl4 soln. under Ar at 0°C, stirred for 30 min; evapd. (vac.), washed with aq. HCl, with EtOH, with ether, recrystd. (toluene), recrystd. (CHCl3);
参考文献
Ott, Kevin C.; deBoer, E. J. M.; Grubbs, Robert H.
Organometallics, 1984 , vol. 3, p. 223 - 230
in tetrahydrofuran under Ar using Schlenk techniques; soln. of Ti(N(SiMe3)CH2CH2C5H4N)Cl3 in THF cooled to -95°C; soln. of NaC5H5 in THF added dropwise; mixt. stirred for 5.5 h; slowly warmed to room temp.; ppt. filtered off; volatiles removed; residue washed (n-hexane); extd. (EtO2); solvent removed; elem. anal;
参考文献
Journal of Organometallic Chemistry, , vol. 632, # 1-2 p. 17 - 26
