ozone T=24.85°C; Oxidation; P=740 Torr; Product distribution;

1.1: 78 percent / O3 / methanol / 2.5 h / -78 °C 2.1: 72 percent / BF3*OEt2 / acetic anhydride / 3 h / 0 °C 3.1: 85 percent / allyl methyl carbonate; DPPE; Bu3SnOMe / Pd(OAc)2 / acetonitrile / 5 h / 80 °C 4.1: 94 percent / DIBAL / tetrahydrofuran; hexane / 1.5 h / -78 °C 5.1: 76 percent / PCC; Celite / CH2Cl2 / 2 h 6.1: 85 percent / imidazole / dimethylformamide 7.1: 73 percent / I2; pyridine / CCl4 8.1: n-BuLi / diethyl ether; hexane 8.2: CuCN / diethyl ether; hexane 8.3: 62 percent / BF3*Et2O / diethyl ether; hexane / -78 °C 9.1: EtMgBr / tetrahydrofuran / 0.17 h / 0 °C 9.2: 66 percent / tetrahydrofuran / 2 h / 0 °C 10.1: Ni(acac)2 / tetrahydrofuran / 0.17 h / 0 °C 10.2: 93 percent / tetrahydrofuran 11.1: 73 percent / NaSEt / dimethylformamide / 12 h / 140 °C 12.1: 84 percent / ZnBr2; MgSO4 / CH2Cl2 / 12 h 13.1: 68 percent / NaSEt / dimethylformamide / 8 h / 120 °C View Scheme

1: 35 percent / potassium bicarbonate, benzonitrile, 30percent hydrogen peroxide / methanol / 24 h / Ambient temperature 2: ammonium nitrate / nitromethane / 4 h / 80 °C View Scheme

1: 35 percent / potassium bicarbonate, benzonitrile, 30percent hydrogen peroxide / methanol / 24 h / Ambient temperature 2: ammonium nitrate / nitromethane / 4 h / 80 °C 3: 80 percent / manganese dioxide / hexane / 2 h / 0 °C 4: silver oxide, sodium hydroxide pellets / H2O / 0.33 h / 55 - 60 °C View Scheme

hydrogen; platinum-alumina(0.6 percent Pt) T=300°C; Yield given;

5 platinum on alumina T=300°C; different size of catalysts; Quantum yield;

pyridine; hydrogen; platinum-alumina(0.6 percentPt) T=300°C; 0.79 h; effects of partial pressures of N2, H2, pyridine; Product distribution;

1: 35 percent / potassium bicarbonate, benzonitrile, 30percent hydrogen peroxide / methanol / 24 h / Ambient temperature 2: ammonium nitrate / nitromethane / 4 h / 80 °C 3: 80 percent / manganese dioxide / hexane / 0.33 h / 0 °C View Scheme

1: 35 percent / potassium bicarbonate, benzonitrile, 30percent hydrogen peroxide / methanol / 24 h / Ambient temperature 2: ammonium nitrate / nitromethane / 4 h / 80 °C View Scheme