gold on carbon; oxygen; sodium hydroxide in water T=60°C; P=7500.75 Torr; Autoclave;
参考文献
Green Chemistry, , vol. 11, # 8 p. 1209 - 1216
→
反应条件
CH3COOH in water addn. of Co(OAc)2 to slurry of Mo salt, pH adjusted to 6 (HOAc), stirring (5 min), hot filtration, crystn. on slow evapn.; elem. anal.;
参考文献
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, , vol. 29, # 7 p. 1123 - 1131
in neat (no solvent) byproducts: methanol; at 475°C;;
参考文献
Journal of the American Chemical Society, , vol. 50, p. 1122 - 1131
→
反应条件
CH3COOH in water addn. of Co(OAc)2 to slurry of Mo salt, pH adjusted to 6 (HOAc), stirring (5 min), hot filtration, crystn. on slow evapn.; elem. anal.;
参考文献
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, , vol. 29, # 7 p. 1123 - 1131