2,2-二甲基-1,3-丙二醇合成路线 （共 467 条）
反应条件
1: tri-p-fluorophenylantimony(III) With boron trichloride in dichloromethane T=0°C; 2 h; 2: With methanol T=20°C; 0.5 h; 3: 3-hydroxy-2,2-dimethylpropanol in methanol T=20°C; 1 h;
参考文献
Yasuike, Shuji; Nakata, Kazuhide; Qin, Weiwei; Kaji, Toshiyuki; Kurita, Jyoji
Chemistry Letters, 2006 , vol. 35, # 12 p. 1402 - 1403
反应条件
in water; benzene 1 h; Inert atmosphereReflux;
参考文献
Carrow, Brad P.; Hartwig, John F.
Journal of the American Chemical Society, 2011 , vol. 133, # 7 p. 2116 - 2119
反应条件
in dichloromethane all reactions under Ar atm.; soln. of BCl3 in CH2Cl2 added to stirred soln. of triarylstibane at 0°C, stirred for 2 h, allowed to warm toroom temp., solvent removed in vac., oil dissolved in MeOH, stirred for 30 min at room temp., diol added; stirred for 1 h, solvent removed in vac., chromy. (silica-gel, hexane/CH2Cl2);
参考文献
Yasuike, Shuji; Nakata, Kazuhide; Qin, Weiwei; Kaji, Toshiyuki; Kurita, Jyoji
Chemistry Letters, 2006 , vol. 35, # 12 p. 1402 - 1403
反应条件
1: potassium acetate / 80 °C 2: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / toluene / 22 h / 80 °C View Scheme
参考文献
Bello, Charles S.; Schmidt-Leithoff, Joachim
Tetrahedron Letters, 2012 , vol. 53, # 46 p. 6230 - 6235,6
反应条件
phosphorus trichoride 1 h;
参考文献
Matos, Robson M.; Gomes De Lima, Luiz Carlos; De Souza, Edward; Barcelos De Souza, Ana Lucia Americano; Gomes De Lima, Miriam Bernardes; Soares Raslan, Delio
Phosphorus, Sulfur and Silicon and the Related Elements, 2002 , vol. 177, # 12 p. 2859 - 2870
反应条件
anhydrous phosphorus trichloride in toluene
参考文献
EASTMAN KODAK COMPANY
Patent: EP382660 A1, 1990 ;
反应条件
thionyl chloride; triphenyl-phosphine oxide T=20 - 115°C; 9.5 h;
参考文献
BASF SE
Patent: US2008/228016 A1, 2008 ;
Location in patent: Page/Page column 5 ;
反应条件
methanol; sodium methylate
参考文献
Popescu, Dragos; Hoogenboom, Richard; Keul, Helmut; Moeller, Martin
Journal of Molecular Catalysis B: Enzymatic, 2010 , vol. 62, # 1 p. 80 - 89
反应条件
sulfuric acid; benzene unter Entfernen des entstehenden Wassers;
参考文献
Loshaek; Fox
Journal of the American Chemical Society, 1953 , vol. 75, p. 3544
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Eastman Kodak Co.
Patent: GB1058550 , 1965 ;
反应条件
methanol; sodium methylate
参考文献
Rohm and Haas Co.
Patent: US2692256 , 1951 ;
