1,1'-双(二苯基膦)二茂铁合成路线 （共 33 条）
反应条件
in benzene-d6 react. of Pd complex with Fe(C5H4PPh2)2 at 75°C;
参考文献
Marquard, Seth L.; Rosenfeld, Devon C.; Hartwig, John F.
Angewandte Chemie - International Edition, 2010 , vol. 49, # 4 p. 793 - 796
反应条件
in acetonitrile 4 h; Heating / reflux;
参考文献
JOHNSON MATTHEY PLC
Patent: WO2007/29031 A1, 2007 ;
Location in patent: Page/Page column 6 ;
反应条件
in tetrahydrofuran; ethanol inert atmosphere, dry solvents; addn. of dppf in THF to soln. of Pd-compd. in EtOH, pptn., stirring (1 h); removal of solvent, washing (water), drying (80°C, 12 h);
参考文献
Housecroft, Catherine E.; Owen, Steven M.; Raithby, Paul R.; Shaykh, Bilal A. M.
Organometallics, 1990 , vol. 9, p. 1617 - 1623
反应条件
in benzene (Ar); addn. of soln. of Pd(PhCN)2Cl2 in benzene to soln. of Fe(C5H4PPh2)2 in benzene; pptn. for a few minutes; stirring overnight; crystn., filtration, washing with benzene, drying under vac.;
参考文献
Gusev, Oleg V.; Peganova, Tat'yana A.; Kalsin, Alexander M.; Vologdin, Nikolai V.; Petrovskii, Pavel V.; Lyssenko, Konstantin A.; Tsvetkov, Aleksey V.; Beletskaya, Irina P.
Organometallics, 2006 , vol. 25, # 11 p. 2750 - 2760
反应条件
in acetone to suspn. of Pd-complex in acetone Fe-complex was added, stirred at roomtemp. for 2 h under inert atm.; vol. was reduced in vac., Et2O was added, stirred for 10 min, filtered, washed with Et2O, dried under vac.;
参考文献
Colacot, Thomas J.; Qian, Hu; Cea-Olivares, Raymundo; Hernandez-Ortega, Simon
Journal of Organometallic Chemistry, 2001 , vol. 637-639, p. 691 - 697
反应条件
in dichloromethane under N2, addn. of complex in CH2Cl2 to soln. of ligand in CH2Cl2, stirred for 25°C for 2 h, white pptn.; evapd. under reduced press., addn. of toluene, heated under reflux for 4 h, pptn., filtered, dried in vac.;
参考文献
Broadwood-Strong, Gillian T. L.; Chaloner, Penny A.; Hitchcock, Peter B.
Polyhedron, 1993 , vol. 12, p. 721 - 730
反应条件
in not given mixing;
参考文献
Moineau, Christophe; Bolitt, Veronique; Sinou, Denis
Journal of the Chemical Society, Chemical Communications, 1995 , # 11 p. 1103 - 1104
反应条件
in tetrahydrofuran under N2, react. at 203 K; not isolated, identified by (31)P-NMR;
参考文献
Polyhedron, , vol. 12, p. 721 - 730
反应条件
in benzene mixt. of soln. of Pd-compound in benzene and soln. of ferrocene derivative in benzene, stirred (12 h, 20°C); filtration, washed with a little benzene, evapn.; elem. anal.;
参考文献
Inorganica Chimica Acta, , vol. 157, p. 259 - 266
反应条件
sodium tetrahydroborate T=105°C; P=760.051 Torr; 0.333333 h; Microwave irradiationInert atmosphereGreen chemistry;
参考文献
Birdwhistell, Kurt R.; Schulz, Brian E.; Dizon, Paula M.
Inorganic Chemistry Communications, 2012 , vol. 26, p. 69 - 71
