Ce(3+) in water
Kinetics; byproducts: Ce(4+); decay of the sulfate radical by reaction with Ce(3+) (2.5, 5.0 and 10.0 mmol/l) in 4 mol/l sulfuric acid soln.;; dosimetry;;
参考文献
Jiang, Pei-Yun; Katsumura, Yosuke; Nagaishi, Ryuji; Domae, Masahumi; Ishikawa, Kenichi; et al.
Journal of the Chemical Society, Faraday Transactions, 1992 , vol. 88, # 12 p. 1653 - 1658
in water
Kinetics; ionic strength varying from 3.0E-3 to 8.3E-2 mol/l by addn. of NaClO4 to the Ar-, O2- or N2O-saturated solns., pH = 4.9; monitoring by spectrophotometry at 450 nm;
参考文献
McElroy, W. J.; Waygood, S. J.
Journal of the Chemical Society, Faraday Transactions, 1990 , vol. 86, # 14 p. 2557 - 2564
→
反应条件
in water
Kinetics; other Radiation; 25°C;
参考文献
Cabelli, Diane E.; Wishart, James F.; Holcman, Jerzy; Meier, Martin; Van Eldik, Rudi
Journal of Physical Chemistry A, 1997 , vol. 101, # 28 p. 5131 - 5136
in water
Kinetics; byproducts: CH3COO; reacting sulfate radicals (produced by laser-flash photolysis of Na2S2O8) with CH3COO(1-) (8.5 - 63.0°C, pH 6.6 - 7.2); monitoring reaction by UV spectroscopy;
参考文献
Huie, Robert E.; Clifton, Carol L.
Journal of Physical Chemistry, 1990 , vol. 94, # 23 p. 8561 - 8567
in water
Kinetics; byproducts: Cl; reacting sulfate radicals (produced by laser-flash photolysis of Na2S2O8) with Cl(1-) (11.4 - 35.0°C, different ionic strengths); monitoring reaction by UV spectroscopy;
参考文献
Huie, Robert E.; Clifton, Carol L.
Journal of Physical Chemistry, 1990 , vol. 94, # 23 p. 8561 - 8567
in water
Kinetics; byproducts: HCO3; reacting sulfate radicals (produced by laser-flash photolysis of Na2S2O8) with HCO3(1-) (13.1 - 57.0°C, pH 7.8 - 8.2); monitoring reaction by UV spectroscopy;
参考文献
Huie, Robert E.; Clifton, Carol L.
Journal of Physical Chemistry, 1990 , vol. 94, # 23 p. 8561 - 8567
in water
Kinetics; Irradiation (UV/VIS); SO4(1-) radicals generated in situ by excimer-laser photolysis, variousOH(1-) concentrations, 298 K; monitoring by time-resolved UV/VIS spectroscopy;
参考文献
Herrmamr; Reese; Zelhrer
Journal of Molecular Structure, 1995 , vol. 348, p. 183 - 186
in perchloric acid
Kinetics; S2O8(2-)/NO3(1-) mixtures in perchloric acid (pH=1) photolyzed at 266 nm; absorbance temporal profiles monitored at 635 and 443 nm;
参考文献
Wine, P. H.; Mauldin, R. L.; Thorn, R. P.
Journal of Physical Chemistry, 1988 , vol. 92, # 5 p. 1156 - 1162
