in ethanol bubbling ethene into stirred soln. of Pt-complex in EtOH to saturation (under N2), slow addn. of B-compd., bubbling ethene (2 h); filtration, washing (H2O, EtOH), drying in air;
参考文献
Journal of Organometallic Chemistry, , vol. 388, # 1+2 p. 215 - 220
in THF-d8 (tetrahydrofuran-d8) react. of the covalent triflate trans-Pt complex with the Re complex salt in THF-d8 under ethylene to a yellow soln.; monitoring by 1H-NMR; formation of an 1:1 mixt.;
in toluene inert atmosphere; addn. of 2 equiv. PPh3 to Pt-complex at -70°C, satn. with C2H4 with warming to room temp.; not isolated, reaction followed by (31)P-NMR spectroscopy;
参考文献
Journal of Organometallic Chemistry, , vol. 590, # 1 p. 25 - 35
in tetrahydrofuran (argon); NMR tube: addn. of the ligand to the Pt complex in THF at -78°C, slight warming for dissoln., recooling to -80°C; NMR monitoring;
参考文献
Chaloner, Penny A.; Broadwood-Strong, Gillian T. L.
Journal of the Chemical Society - Dalton Transactions, 1996 , # 6 p. 1039 - 1043
