tetrachloromethane in 2-methyl cyclohexane
Irradiation (UV/VIS); generation of (C5H5)FeMn(CO)6 by UV-irradiation at 93K in methylcyclohexane glass, thermal react. with photogenerated CO on warming to 140K in presence of CCl4;; detn. by IR and UV;;
参考文献
Pope, Keith R.; Wrighton, Mark S.
Journal of the American Chemical Society, 1987 , vol. 109, # 15 p. 4545 - 4552
tetrachloromethane in tetrahydrofuran
Irradiation (UV/VIS); irradn. of Fe complex and phosphite ligand in THF at -78°C, CCL4vac. distd. in soln., warmed to room temp.; not isolated, detected by IR;
参考文献
Tyler, David R.; Schmidt, Maryke A.; Gray, Harry B.
Journal of the American Chemical Society, 1983 , vol. 105, # 19 p. 6018 - 6021
Cl2 in tetrachloromethane
byproducts: 1-chloro-1-methyl-1-silacyclobutane; addn. of stoich. amt. of Cl2 to Fe-complex soln.; evapn. (vac.), extn. of red residue (C6H6), decantation, evapn., treatment with hexane, crystn. (0°C);
参考文献
Cundy, Colin S.; Lappert, Michael F.; Choi-Kwan Yuen
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1978 , p. 427 - 433
SO2Cl2 in tetrahydrofuran
byproducts: CO; Room temp., N2-atmosphere.;
参考文献
Manning, A. R.; McNally, Gerard; Cunningham, Desmond; McArdle, Patrick; Simmie, John M.
Journal of Organometallic Chemistry, 1988 , vol. 338, p. 383 - 392
tetrachloromethane in 2-methyl cyclohexane
Irradiation (UV/VIS); generation of (C5H5)FeMn(CO)6 by UV-irradiation at 93K in methylcyclohexane glass, thermal react. in presence of a 10fold excess of PR3 on warming up and annealing in presence of CCl4;; detn. by IR and UV;;
参考文献
Pope, Keith R.; Wrighton, Mark S.
Journal of the American Chemical Society, 1987 , vol. 109, # 15 p. 4545 - 4552
tetrachloromethane in 2-methyl cyclohexane
Irradiation (UV/VIS); generation of (C5H5)FeMn(CO)6 by UV-irradiation at 93K in methylcyclohexane glass, thermal react. in presence of a 10fold excess of PR3 on warming up and annealing in presence of CCl4;; detn. by IR and UV;;
参考文献
Pope, Keith R.; Wrighton, Mark S.
Journal of the American Chemical Society, 1987 , vol. 109, # 15 p. 4545 - 4552
