in neat (no solvent, solid phase)
under N2, at ca. 120°C or photolytically;
参考文献
Banister, Arthur J.; Hauptman, Zdenek V.; Passmore, Jack; Wong, Chi-Mingh; White, Peter S.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1986 , p. 2371 - 2380
in neat (no solvent, gas phase)
by heating to 130-150°C at low pressure; at temp. > 450°CS2, N2, S2N2 are produced; at temp. < 130°C S4N2, S4N4, S2N2 areproduced; various product ratio for various conditions; further products; detected by He I photoelectron spectroscopy and quadrupole mass specrometry;
参考文献
Lau, W. M.; Westwood, N. P. C.; Palmer, M. H.
Journal of the American Chemical Society, 1986 , vol. 108, # 12 p. 3229 - 3237
in gaseous matrix
heating of (SN)x in a discharge tube at 130°C while 1 mmol/h of Ar was allowed to sweep the (SN)x vapor; condensation on cold window; not isolated, detected by IR;
参考文献
Hassanzadeh, Parviz; Andrews, Lester
Journal of the American Chemical Society, 1992 , vol. 114, # 1 p. 83 - 91
in neat (no solvent, gas phase)
by heating to 130-150°C at low pressure; at temp. > 450°CS2, N2, S2N2 are produced; at temp. < 130°C S4N2, S4N4, S2N2 areproduced; various product ratio for various conditions; further products; detected by He I photoelectron spectroscopy and quadrupole mass specrometry;
参考文献
Lau, W. M.; Westwood, N. P. C.; Palmer, M. H.
Journal of the American Chemical Society, 1986 , vol. 108, # 12 p. 3229 - 3237
in gaseous matrix
heating of (SN)x in a discharge tube at 130°C while 1 mmol/h of Ar was allowed to sweep the (SN)x vapor; condensation on cold window; not isolated, detected by IR;
参考文献
Hassanzadeh, Parviz; Andrews, Lester
Journal of the American Chemical Society, 1992 , vol. 114, # 1 p. 83 - 91