lithium aluminium tetrahydride; meta-chloroperoxybenzoic acid 2.) ether, 30 min, reflux; study of the regioselectivity of autoxidation by reduction of the corresponding oxidation-mixture; MechanismProduct distribution;
lithium aluminium tetrahydride; meta-chloroperoxybenzoic acid 2.) ether, 30 min, reflux; study of the regioselectivity of autoxidation by reduction of the corresponding oxidation-mixture; MechanismProduct distribution;
1: toluene With n-butyllithium; LiK(OCH2CH2NMe2)2; Mg(OCH2CH2OEt)2 in various solvent(s)
T=20°C; Metallation; 0.5 h;
2: ethene in various solvent(s)
T=80°C; Alkylation; P=7600.51 Torr; 24 h; Further stages.;
参考文献
Steele, Barry R.; Screttas, Constantinos G.
Journal of the American Chemical Society, 2000 , vol. 122, # 10 p. 2391 - 2392
