1,2,3,4,4A,5,6,7-八氢萘合成路线 (共 38 条)
反应条件
diethyl ether; platinum T=15 - 16°C; Hydrogenation; cis-decalin;
参考文献
Hueckel et al.
Justus Liebigs Annalen der Chemie, 1929 , vol. 474, p. 143
参考文献
Schuikin
Uc. Zap. Moskovsk. Univ., 1934 , # 3 p. 197,200
Chem. Zentralbl., 1935 , vol. 106, # II p. 3650
反应条件
diethyl ether; platinum T=15 - 16°C; Hydrogenation; cis-decalin;
参考文献
Hueckel et al.
Justus Liebigs Annalen der Chemie, 1929 , vol. 474, p. 143
反应条件
calcium; ammonium chloride
1.) methylamine, ethylenediamine, 23h, 2.) 0 deg C, diethyl ether; Yield given. Yields of byproduct given;
参考文献
Benkeser, Robert A.; Belmonte, Frank G.; Kang, Jahyo
Journal of Organic Chemistry, 1983 , vol. 48, # 17 p. 2796 - 2802
反应条件
hydrogen; lt;Sigt;-ORh(allyl)H in hexane
T=22°C; P=25857.4 Torr; rate in turnovers/h, PMe3 presence; Mechanism;
参考文献
Ward, Michael D.; Schwartz, Jeffrey
Journal of the American Chemical Society, 1981 , vol. 103, # 17 p. 5253 - 5255
反应条件
sulfuryl dichloride; Co(II)TMeOPP in benzene
T=85°C; Yield given. Yields of byproduct given;
参考文献
Khanna, Vibha; Tamilselvan, Pitchiah; Kalra, Swinder Jeet Singh; Iqbal, Javed
Tetrahedron Letters, 1994 , vol. 35, # 32 p. 5935 - 5938
反应条件
calcium shot; ethylenediamine; methylamine
24 h; Yields of byproduct given;
参考文献
Benkeser, Robert A.; Belmonte, Frank G.; Yang, Mei-Hui
Synthetic Communications, 1983 , vol. 13, # 13 p. 1103 - 1116
反应条件
white sand; calcium; tert-butyl alcohol in ethylenediamine
T=0°C; 24 h; Yield given. Yields of byproduct given;
参考文献
Benkeser, Robert A.; Laugal, James A.; Rappa, Angela
Tetrahedron Letters, 1984 , vol. 25, # 20 p. 2089 - 2092
反应条件
1: 1.) TMSCl, NaI / 1.) acetonitrile
2: 88 percent / Et3N
3: 30 percent / NaI / acetone
4: 1.) PPh3, 2.) CH3S(O)CH2Na / 1.) benzene, 2.) DMSO
View Scheme
参考文献
Iyer, Ramnath S.; Kuo, Gee-Hong; Helquist, Paul
Journal of Organic Chemistry, 1985 , vol. 50, # 26 p. 5898 - 5900
反应条件
ammonia; sodium in methanol
T=-75 - -33°C; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Beger, J.; Thomas, B.; Vogel, T.; Kirmse, K.; Lang, R.
Journal fuer Praktische Chemie (Leipzig), 1991 , vol. 333, # 3 p. 481 - 488