双环[2.2.2]辛烷-1-胺合成路线 （共 6 条）
反应条件
sodium azide; sulfuric acid in chloroform
参考文献
Fischer,H.P.; Grob,C.A.
Helvetica Chimica Acta, 1964 , vol. 47, # 2 p. 564 - 567
参考文献
Chae, Woo-Ki; Baughman, Sharon A.; Engel, Paul S.; Bruch, Manfred; Oezmeral, Cenan; et al.
Journal of the American Chemical Society, 1981 , vol. 103, # 16 p. 4824 - 4833
反应条件
1: 85 percent / 30percent fuming H2CO4, conc. H2SO4 / 2.5 h / 0 °C 2: 4.74 g / conc. HCl / 48 h / Heating View Scheme
参考文献
Chae, Woo-Ki; Baughman, Sharon A.; Engel, Paul S.; Bruch, Manfred; Oezmeral, Cenan; et al.
Journal of the American Chemical Society, 1981 , vol. 103, # 16 p. 4824 - 4833
反应条件
1: LiAlH4 2: 85 percent / 30percent fuming H2CO4, conc. H2SO4 / 2.5 h / 0 °C 3: 4.74 g / conc. HCl / 48 h / Heating View Scheme
参考文献
Chae, Woo-Ki; Baughman, Sharon A.; Engel, Paul S.; Bruch, Manfred; Oezmeral, Cenan; et al.
Journal of the American Chemical Society, 1981 , vol. 103, # 16 p. 4824 - 4833
反应条件
hydrogenchloride T=180°C;
参考文献
Fischer,H.P.; Grob,C.A.
Helvetica Chimica Acta, 1964 , vol. 47, # 2 p. 564 - 567
反应条件
1: Br2, NaOH 2: aq. HCl / 180 °C View Scheme
参考文献
Fischer,H.P.; Grob,C.A.
Helvetica Chimica Acta, 1964 , vol. 47, # 2 p. 564 - 567
