119072-55-8合成路线 （共 225 条）
反应条件
titanium tetrachloride T=-78 - -30°C;
参考文献
Ito, Yoshihiko; Kato, Hidehito; Imai, Hiroshi; Saegusa, Takeo
Journal of the American Chemical Society, 1982 , vol. 104, # 23 p. 6449 - 6450
反应条件
tetrakis(triphenylphosphine) palladium(0) in 1,4-dioxane T=20°C; 2 h;
参考文献
Journal of Organic Chemistry, , vol. 78, # 7 p. 3009 - 3020
反应条件
in N,N-dimethyl-formamide T=120°C; 24 h; Inert atmosphere;
参考文献
Journal of Organic Chemistry, , vol. 78, # 4 p. 1471 - 1477
反应条件
in tetrahydrofuran N2; 0°C; equiv. amts. in presence of 3 equiv. (CH3)3CNC; GLC;
参考文献
Tsuda, Tetsuo; Chujo, Yoshiki; Saegusa, Takeo
Journal of the American Chemical Society, 1980 , vol. 102, # 1 p. 431 - 433
反应条件
titanium tetrachloride in dichloromethane T=-78 - 20°C; Inert atmosphere;
参考文献
Kyowa Hakko Kirin Co., Ltd.
Patent: EP2090570 A1, 2009 ;
Location in patent: Page/Page column 95 ;
EP 2090570 A1
反应条件
in dichloromethane W-compd. and isocyanide stirred for 20 min, addn. of phosphine, stirred overnight; volume reduced, chromy. on an alumina column with CH2Cl2-hexane, evapn. of solvent, addn. of methanol; elem. anal.;
参考文献
Detter, Lisa D.; Conner, Kay A.; Rothwell, Arlene P.; Walton, Richard A.
Inorganica Chimica Acta, 1988 , vol. 143, p. 109 - 118
反应条件
in dichloromethane W-compd. and isocyanide stirred for 30 min, addn. of phosphine, stirred overnight; volume reduced, chromy. on an alumina column with CH2Cl2-hexane, solvent stripped off, addn. of petroleum ether, cooled to 0°C, recrystn. (CH2Cl2-petroleum ether); elem. anal.;
参考文献
Detter, Lisa D.; Conner, Kay A.; Rothwell, Arlene P.; Walton, Richard A.
Inorganica Chimica Acta, 1988 , vol. 143, p. 109 - 118
反应条件
formic acid in methanol; hexane; ethyl acetate; toluene
参考文献
Merck and Co., Inc.
Patent: US6156895 A1, 2000 ;
US 6156895 A
Title/Abstract Full Text Show Details
Merck and Co., Inc.
Patent: US5977364 A1, 1999 ;
US 5977364 A
反应条件
nickel T=170 - 180°C; Hydrogenation;
参考文献
Sabatier; Mailhe
Annales de Chimie (Cachan, France), 1909 , vol. <8>16, p. 107
Full Text Show Details
Sabatier; Mailhe
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1907 , vol. 144, p. 956
Bulletin de la Societe Chimique de France, 1907 , vol. <4>1, p. 614
反应条件
in diethyl ether addn. of org. compd. to cold soln. (-40°C) of Ni-complex in Et2O, warming to room temp., stirring (5 h); removal of volatiles (vac.), extn. (petroleum ether/Et2O), filtration, concn., pptn. on cooling (-30°C); elem. anal.;
参考文献
Organometallics, , vol. 9, # 3 p. 583 - 588
