反应条件
magnesium in diethyl ether
byproducts: MgClBr; under Ar; prepn. of Grignard reagent in Et2O (yield: 85-90percent), sepn. of excess Mg, dropwise addn. of the Grignard soln. to germane soln., refluxed, 4 h; addn. of 20percent NH4Cl, sepn., ethereal phase washed (distd. H2O, aq. NaHCO3), dried (MgSO4), sepn., fractional distn.; elem. anal.;
参考文献
Popowski, E.; Marekowa, U.; Reiske, T.; Schulz, H.; Kelling, H.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1990 , vol. 583, p. 195 - 204