Ti(OCH(CH3)2)4 in neat (no solvent) under Ar, addn. of 1.5 equiv. of catecholborane to mixt. of 1.0 equiv. decene and 0.1 equiv. Ti(OCH(CH3)2)4, stirred for 12 h; not isolated, identified by (11)B-NMR spectroscopy;
参考文献
Burgess, Kevin; Donk, Wilfed A. van der
Organometallics, 1994 , vol. 13, p. 3616 - 3620
Heeney, Martin J.; Al-Raqa, Shaya A.; Auger, Aurelien; Burnham, Paul M.; Cammidge, Andrew N.; Chambrier, Isabelle; Cook, Michael J.
Journal of Porphyrins and Phthalocyanines, 2013 , vol. 17, # 8-9 p. 649 - 664
in tetrahydrofuran alkene was hydroborated with BH3*THF in THF soln. at 0°C for 1 h; not isolated from the soln.;
参考文献
Kabalka, George W.; Henderson, David A.; Varma, Rajender S.
Organometallics, 1987 , vol. 6, p. 1369 - 1370
→
反应条件
in diethyl ether 3 equiv of LiBH4 adding to a soln. of the ester in the presence of 3 equiv of the olefine in Et2O at 25°C; hydrolyzing; detected by (11)B NMR spectrum;
参考文献
Brown, Herbert C.; Narasimhan, S.
Organometallics, 1982 , vol. 1, p. 762 - 765
