2,2,3,4-四甲基戊烷合成路线 (共 12 条)
反应条件
hydrogen; palladium on activated charcoal in ethanol T=80°C; P=220652 Torr; Yield given;
参考文献
Hellmann, Siegried; Beckhaus, Hans-Dieter; Ruechardt, Christoph
Chemische Berichte, 1983 , vol. 116, # 6 p. 2219 - 2237
反应条件
aluminum oxide; silica gel T=112°C; P=25742.8 Torr;
参考文献
Johnson; Fawcett
Journal of the American Chemical Society, 1946 , vol. 68, p. 1417
反应条件
1: H2SO4 2: Al2O3+SiO2 / 112 °C / 25742.8 Torr View Scheme
参考文献
Johnson; Fawcett
Journal of the American Chemical Society, 1946 , vol. 68, p. 1417
反应条件
1: HMPT / 3 h / 220 °C 2: H2 / 10percent Pd-C / ethanol / 80 °C / 220652 Torr View Scheme
参考文献
Hellmann, Siegried; Beckhaus, Hans-Dieter; Ruechardt, Christoph
Chemische Berichte, 1983 , vol. 116, # 6 p. 2219 - 2237
反应条件
sulfuric acid Hydrieren des erhaltenen Kohlenwasserstoff-Gemisches an Nickel in Gegnwart von Wasser bei 160grad;
参考文献
Johnson; Fawcett
Journal of the American Chemical Society, 1946 , vol. 68, p. 1417
反应条件
nickel kieselguhr T=160°C; Hydrogenation.unter Druck;
参考文献
Howard et al.
Journal of Research of the National Bureau of Standards (United States), 1947 , vol. 38, p. 391
Chem. Zentralbl., 1947 , vol. 118, p. 5291
反应条件
mercury T=70°C; Irradiation.mit UV-Licht;
参考文献
Standard Oil Devel. Co.
Patent: US2657985 , 1950 ;
反应条件
1: benzene 2: nickel kieselguhr / 160 °C / Hydrogenation.unter Druck View Scheme
参考文献
Howard et al.
Journal of Research of the National Bureau of Standards (United States), 1947 , vol. 38, p. 391
Chem. Zentralbl., 1947 , vol. 118, p. 5291
反应条件
thiophenol in 1,3,5-trimethyl-benzene T=254°C; pyrolyse, ΔH*, ΔS*, ΔG*, strain energy, "strain energy of dissociation"; KineticsRate constantThermodynamic data;
参考文献
Hellmann, Siegried; Beckhaus, Hans-Dieter; Ruechardt, Christoph
Chemische Berichte, 1983 , vol. 116, # 6 p. 2238 - 2249
反应条件
1: β-naphthalenesulfonic acid 2: nickel kieselguhr / 160 °C / Hydrogenation.unter Druck View Scheme
参考文献
Howard et al.
Journal of Research of the National Bureau of Standards (United States), 1947 , vol. 38, p. 391
Chem. Zentralbl., 1947 , vol. 118, p. 5291