10,15-二氢-2,3,7,8,12,13-六甲氧基-5H-三苯并[a,d,g]环壬烯合成路线 （共 28 条）
反应条件
acetic anhydride; copper(II) nitrate
参考文献
Sato,T. et al.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1973 , p. 891 - 895
反应条件
boron tribromide in dichloromethane T=0°C; 2.41667 h; Reflux;
参考文献
Roche, Cecile; Sun, Hao-Jan; Prendergast, Margaret E.; Leowanawat, Pawaret; Partridge, Benjamin E.; Heiney, Paul A.; Araoka, Fumito; Graf, Robert; Spiess, Hans W.; Zeng, Xianbingon; Ungar, Goran; Percec, Virgil
Journal of the American Chemical Society, 2014 , vol. 136, # 19 p. 7169 - 7185
反应条件
Tonsil Actisil FF in neat (no solvent)
T=85°C; P=750.075 Torr; 0.0333333 h; Microwave irradiation; TimeTemperature;
参考文献
Miranda, Rene; Valencia-Vazquez, Omar; Maya-Vega, Carlos Abel; Nicolas-Vazquez, Ines; Vargas-Rodriguez, Yolanda Marina; Morales-Serna, Jose Antonio; Garcia-Rios, Erendira; Salmon, Manuel
Molecules, 2013 , vol. 18, # 10 p. 12820 - 12844
反应条件
Nafion-H in dichloromethane
2 h; Heating;
参考文献
Yamato, Takehiko; Hideshima, Chieko; Prakash, G. K. Surya; Olah, George A.
Journal of Organic Chemistry, 1991 , vol. 56, # 6 p. 2089 - 2091
反应条件
boron trifluoride diethyl etherate in 1,2-dichloro-ethane
T=30°C; 3 h; Inert atmosphere;
参考文献
Ogoshi, Tomoki; Kitajima, Keisuke; Umeda, Kenji; Hiramitsu, Sachi; Kanai, Suguru; Fujinami, Shuhei; Yamagishi, Tada-aki; Nakamoto, Yoshiaki
Tetrahedron, 2009 , vol. 65, # 51 p. 10644 - 10649
反应条件
chloro-trimethyl-silane; sulfuric acid; acetic anhydride in diethyl ether
T=20°C; 2 h;
参考文献
Roe, Caroline; Sandoe, Elizabeth J.; Richard Stephenson
Tetrahedron Letters, 2010 , vol. 51, # 4 p. 591 - 595
反应条件
trifluoroacetic acid in chloroform
T=0°C; 24 h;
参考文献
Al-Farhan, Emile; Keehn, Phillip M.; Stevenson, Robert
Tetrahedron Letters, 1992 , vol. 33, # 25 p. 3591 - 3594
参考文献
Umezawa,B. et al.
Chemical and Pharmaceutical Bulletin, 1969 , vol. 17, p. 2240 - 2244
反应条件
1: (i) aq. H2SO4, dioxane, (ii) /BRN= 635994/, aq. KOH, MeOH
2: aq. HCl / ethanol
View Scheme
参考文献
White,J.D.; Gesner,B.D.
Tetrahedron, 1974 , vol. 30, p. 2273 - 2277
反应条件
1: 64 percent / LiAlH4 / tetrahydrofuran / 1.5 h / 35 °C
2: PBr3 / CH2Cl2 / 1.) 0 deg C, 1.5 h, 2.) r.t., 1 h
3: ZnCl2, NaBH3CN / tetrahydrofuran / 5 h / Ambient temperature
View Scheme
参考文献
Hara, Hiroshi; Watanabe, Shin-ichi; Yamada, Makoto; Hoshino, Osamu
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1996 , # 7 p. 741 - 746
