(8S,9S,10R,11S,13S,14S,16R,17S)-11,16,17-三羟基-17-(2-羟基乙酰基)-10,13-二甲基-2,6,7,8,9,11,12,14,15,16-十氢-1H-环戊并[a]菲-3-酮合成路线 （共 4 条）
1171-81-9(8S,9S,10R,11S,13S,14S,16R,17S)-11,16,17-三羟基-17-(2-羟基乙酰基)-10,13-二甲基-2,6,7,8,9,11,12,14,15,16-十氢-1H-环戊并[a]菲-3-酮
→
反应条件
1: mit Hilfe von Corynebacterium simplex oder Nocardia corallina 2: pyridine 3: SOCl2; pyridine 4: aqueous HClO4; dioxane 5: potassium acetate; ethanol 6: CHCl3; HF 7: methanol.KOH 8: acetone; hydrochloric acid View Scheme
参考文献
Bernstein et al.
Journal of the American Chemical Society, 1959 , vol. 81, p. 1696,1699
1171-81-9(8S,9S,10R,11S,13S,14S,16R,17S)-11,16,17-三羟基-17-(2-羟基乙酰基)-10,13-二甲基-2,6,7,8,9,11,12,14,15,16-十氢-1H-环戊并[a]菲-3-酮
→
反应条件
1: mit Hilfe von Corynebacterium simplex oder Nocardia corallina 2: pyridine 3: SOCl2; pyridine 4: aqueous HClO4; dioxane 5: potassium acetate; ethanol 6: CHCl3; HF View Scheme
参考文献
Bernstein et al.
Journal of the American Chemical Society, 1959 , vol. 81, p. 1696,1699
1171-81-9(8S,9S,10R,11S,13S,14S,16R,17S)-11,16,17-三羟基-17-(2-羟基乙酰基)-10,13-二甲基-2,6,7,8,9,11,12,14,15,16-十氢-1H-环戊并[a]菲-3-酮
→
反应条件
mit Hilfe von Corynebacterium simplex oder Nocardia corallina;
参考文献
Bernstein et al.
Journal of the American Chemical Society, 1959 , vol. 81, p. 1696,1699
1171-81-9(8S,9S,10R,11S,13S,14S,16R,17S)-11,16,17-三羟基-17-(2-羟基乙酰基)-10,13-二甲基-2,6,7,8,9,11,12,14,15,16-十氢-1H-环戊并[a]菲-3-酮
→
反应条件
1: mit Hilfe von Corynebacterium simplex oder Nocardia corallina 2: pyridine 3: SOCl2; pyridine 4: aqueous HClO4; dioxane 5: potassium acetate; ethanol 6: CHCl3; HF 7: methanol.KOH View Scheme
参考文献
Bernstein et al.
Journal of the American Chemical Society, 1959 , vol. 81, p. 1696,1699
