1: H2 / Ru(OCOCF3)2<(S)-tolbinap> / methanol / 100 h / 30 °C / 76000.1 Torr View Scheme

1: H2 / Ru(OCOCF3)2<(S)-tolbinap> / methanol / 100 h / 30 °C / 76000.1 Torr View Scheme

lt;Ru(OAc)2((S)-(6,6'-dimethylbiphenyl-2,2'-diyl)bis(diphenylphosphine))gt;; hydrogen in methanol T=100°C; P=45003.6 Torr; 24 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

hydrogen; Ru(OCOCF3)2((S)-tolbinap) in methanol T=30°C; P=76000.1 Torr; 100 h;