2-甲基-3-丁炔-2-醇合成路线 （共 621 条）
参考文献
I.G.Farbenind.
Patent: DE728466 , 1938 ;
DRP/DRBP Org.Chem.
反应条件
sodium tetrahydroborate 1.) ethanol, room t.; 2.) ethanol, reflux, 20 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Journal of Organometallic Chemistry, , vol. 326, p. 35 - 48
反应条件
1: 42 percent / KOH / 1 h / 70 °C 2: 1.) Co2(CO)8 / 1.) petroleum ether, 25 deg C, 2.) isooctane, 60 deg C, 24 h View Scheme
参考文献
Smit, V. A.; Simonyan, S. O.; Tarasov, V. A.; Gybin, A. S.; Mikaelyan, G. S.; et al.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1988 , vol. 37, # 12 p. 2526 - 2535
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1988 , # 12 p. 2802 - 2812
反应条件
sodium hydroxide; 2,2'-azo-bisisobutyronitrile in dichloromethane T=10°C; Product distribution; Further Variations:ReagentsSolventsTemperatures;
参考文献
Synthesis, , # 3 p. 361 - 364
反应条件
urea; chloroplatinic acid
参考文献
Shin-Etsu Chemical Co., Ltd.
Patent: US5072012 A1, 1991 ;
反应条件
pyridine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; triphenylphosphine 0.666667 h; Heating;
参考文献
Katzsch, Felix; Eissmann, Diana; Weber, Edwin
Structural Chemistry, 2012 , vol. 23, # 1 p. 245 - 255
反应条件
copper(l) iodide; (Ph3)2PdCl2; triphenylphosphine; triethylamine Sonogashira reaction; 68 h; Heating;
参考文献
Rosowsky, Andre; Forsch, Ronald A.; Sibley, Carol Hopkins; Inderlied, Clark B.; Queener, Sherry F.
Journal of Medicinal Chemistry, 2004 , vol. 47, # 6 p. 1475 - 1486
反应条件
sodium hydroxide; 2,2'-azo-bisisobutyronitrile in dichloromethane T=10°C; Product distribution; Further Variations:ReagentsSolventsTemperatures;
参考文献
Synthesis, , # 3 p. 361 - 364
反应条件
sodium hydroxide; 2,2'-azo-bisisobutyronitrile in dichloromethane T=10°C; Product distribution; Further Variations:ReagentsSolventsTemperatures;
参考文献
Synthesis, , # 3 p. 361 - 364
反应条件
sodium hydroxide; 2,2'-azo-bisisobutyronitrile in dichloromethane T=0 - 20°C; 3 h; Product distribution; Further Variations:SolventsTemperaturesreaction time;
参考文献
Calleja-Rubio; Crette; Blancou
Synthesis, 2003 , # 3 p. 361 - 364
