in hexadeuterioacetone to cold (-78 °C) soln. of Ti complex in acetone-d6 added soln. of HgCl2 in acetone-d6 under N2; warmed to room temp., monitored by NMR;
in acetone HgCl2 in acetone was added to Sn compd. at 0°C, stirred for 3 h at 20°C; acetone was evapd., remaining mixture was extd. with CCl4, CH3HgCl was sepd., distn. at 135°C at 2E-2 Torr; elem. anal.;
in hexadeuterioacetone to cold (-78 °C) soln. of Ti complex in acetone-d6 added soln. of HgCl2 in acetone-d6 under N2; warmed to room temp., monitored by NMR;
in hexadeuterioacetone to cold (-78 °C) soln. of Ti complex in acetone-d6 added soln. of HgCl2 in acetone-d6 under N2; warmed to room temp., monitored by NMR;
seawater or NaCl in water byproducts: Pb(II); a mixt. of Me3PbOAc and Hg(OAc)2 was prepared in seawater or NaCl soln., placed in a flask sealed from light for 12 h; monitored by 207Pb/199Hg NMR (complete formation of MeHgCl) and electrochemical measurments;
参考文献
Australian Journal of Chemistry, , vol. 39, p. 1167 - 1176
sodium chloride in water (CH3)2SnCl2 was added to a soln. of HgCl2 in aq. NaCl (artificial seawater), the flask was sealed from light, shaken for 30 d at room temp.; monitored by 199Hg NMR;
参考文献
Australian Journal of Chemistry, , vol. 39, p. 1167 - 1176
