S2Cl2 in carbon disulfide byproducts: (C5H5)2TiCl2; stirring reaction mixture for 3 min at 20 ° C; removing (C5H5)2TiCl2 by filtration; concentration to 50 ml; precipitation of orange crystals at -78 ° C; recrystallization from CS2 (dissolution at 20 ° C, crystallization at -78 ° C);

in carbon disulfide react. of Ti-compd. and S2Cl2 in CS2 at 20°C;

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With  triphenylphosphine in  dichloromethane  addition of triphenylphosphine to a refluxing soln. of educt during 45 min; refluxing for a further hour, crystn.; filtration; washing with pentane, elem. anal.;